209808994-energie-si-mediu-proiect-dinca.pdf

N := 11

Ngr := 11

Compozitia elementara a carbunelui si gazului natural: Lignit c := 0.4 + 0.002⋅ N = 0.422 h := 0.06 − 0.0012⋅ N = 0.0468 n2 := 0.02 − 0.0003⋅ N = 0.0167 o2 := 0.015 − 0.0002⋅ N = 0.0128 s := 0.015 + 0.0015⋅ N = 0.0315 w := 0.15 + 0.002⋅ N = 0.172 A := 1 − c − h − n2 − o2 − s − w = 0.2982 Gaz natural: ch4 := 0.8 + 0.0004⋅ N = 0.8044 c2h6 := 0.023 + 0.0002⋅ N = 0.0252 c3h8 := 0.033 + 0.0003⋅ N = 0.0363 c4h10 := 0.032 + 0.0002⋅ N = 0.0342 c5h12 := 0.03 + 0.0005⋅ N = 0.0355 −3

h2s := 0.007 − 0.00003 ⋅ N = 6.67 × 10

co2 := 1 − ch4 − c2h6 − c3h8 − c4h10 − c5h12 − h2s = 0.05773

Numarul consumatorilor: 4

Npers := 2000 + 450 ⋅ N + 650 ⋅ Ngr = 1.41 × 10

Energia electrica consumata de o persoana: Epers := 4.5

MWh an⋅ om

Energia anuala: 4

Ean := Npers⋅ Epers = 6.345 × 10 Durata anuala de functionare

3

daf := 8500 − 150 ⋅ N − 125 ⋅ Ngr = 5.475 × 10 Durata de viata dv := 1

an

Distanta de transport pentru carbune Dc := 250 + 10⋅ N = 360 1

3

Dgn := 1700 + 25⋅ N = 1.975 × 10 Puterea calorifica inferioara Carbune

4

PCIc := ( 81.3⋅ c + 243 ⋅ h + 15n2 + 45.6⋅ s − 25.3⋅ o2 − 6⋅ w) ⋅ 418.68 = 1.926433 × 10

Gaz natural ch4⋅ 16 + c2h6⋅ 30 + c3h8⋅ 44 + c4h10⋅ 58 + c5h12⋅ 72 + h2s⋅ 34 + co2⋅ 44 ρgn := = 1.00518 22.414 PCIch4 := 35764 PCIc2h6 := 63670

kJ

(m3)N

PCIc3h8 := 91138 PCIc4h10 := 118500 PCIc5h12 := 145900 PCIh2s := 23354

4

PCIgn1 := ch4⋅ PCIch4 + c2h6⋅ PCIc2h6 + c3h8⋅ PCIc3h8 = 3.368136 × 10

3

PCIgn2 := c4h10⋅ PCIc4h10 + c5h12⋅ PCIc5h12 + h2s⋅ PCIh2s = 9.387921 × 10

4

PCIgn := PCIgn1 + PCIgn2 = 4.306928 × 10

PCIgnn :=

PCIgn ρgn

4

= 4.284734 × 10

kJ

(m3)N

kJ kg

Eficienteleproceselor pe durata ciclului de viata Procesul de extractie ηexc := 0.9 − 0.004⋅ N = 0.856 ηexgn := 0.91 + 0.002⋅ N = 0.932 Procesul de tratare ηtrc := 0.85 + 0.003⋅ N = 0.883 ηtrgn := 0.88 + 0.002⋅ N = 0.902 Procesul de transport ηtpc := 0.9 − 0.006⋅ N = 0.834 ηtpgn := 0.85 + 0.003⋅ N = 0.883 Procesul de combustie 2

ηc1c := 0.42 − 0.002⋅ N = 0.398 ηc2c := 0.45 − 0.003⋅ N = 0.417 ηcgn := 0.5 + 0.005⋅ N = 0.555 Determinarea cantitatii de combustibil necesara in cadrul fiecarei etape si filiere energetice Filiera de carbune (ardere pulverizata) 6

Ean⋅ 3.6⋅ 10

Mac :=

ηc1c⋅ PCIc

Matp :=

Mac

Matr :=

Matp

Maex :=

Matr

ηtpc

ηtrc

ηexc

7

= 2.979183 × 10

7

= 3.572162 × 10

7

= 4.045483 × 10

= 4.726032 × 10

7

Filiera de gaz natural

Mbc :=

Mbtp :=

Mbtr :=

Mbex :=

Ean⋅ 3.6⋅ 10

6

ηcgn ⋅ PCIgnn Mbc

= 1.087819 × 10

ηtpgn Mbtp ηtrgn

= 9.605441 × 10

= 1.206008 × 10

Mbtr ηexgn

= 1.294 × 10

6

7

7

7

Filiera de carbune (ardere in pat fluidizat)

6

Mcc :=

Ean⋅ 3.6⋅ 10

ηc2c⋅ PCIc

Mctp :=

Mcc

Mctr :=

Mctp

Mcex :=

Mctr

ηtpc

ηtrc

ηexc

7

= 2.843441 × 10

7

= 3.409401 × 10

7

= 3.861157 × 10

= 4.510697 × 10

7

3

Emisiile specifice pentru fiecare filiera energetica si etapa

Filiera de carbune Etapa de extractie NH3exC := 0.0494 + 0.0003⋅ N = 0.0527 CO2exC := 3.643 + 0.08⋅ N = 4.523 COexC := ( 0.00381 + 0.0002⋅ N) = 6.01 × 10

−3 −9

HCLexC := 0.00000000131 + 0.00000000005 ⋅ N = 1.86 × 10

−9

HFexC := 0.00000000243 + 0.00000000003 ⋅ N = 2.76 × 10

H2SexC := 0.00000000103 + 0.00000000003 ⋅ N = 1.36 × 10

−9

CH4exC := 0.6391 + 0.006⋅ N = 0.7051 NOxexC := 0.0191 + 0.0007⋅ N = 0.0268 −4

N2OexC := 0.000316 + 0.0000138 ⋅ N = 4.678 × 10 PrexC := 0.00789 + 0.00045 ⋅ N = 0.01284 SO2exC := 0.0412 + 0.002⋅ N = 0.0632

Etapa de tratare

NH3trC := ( 0.0245 + 0.0003⋅ N) = 0.0278 CO2trC := 3.74 + 0.08⋅ N = 4.62 −3

COtrC := 0.00322 + 0.0002⋅ N = 5.42 × 10

−9

HCLtrC := 0.00000000305 + 0.00000000005 ⋅ N = 3.6 × 10

−9

HFtrC := 0.00000000526 + 0.00000000003 ⋅ N = 5.59 × 10

H2StrC := 0.00000000112 + 0.00000000003 ⋅ N = 1.45 × 10

−9

−3

CH4trC := 0.00738 + 0.00006 ⋅ N = 8.04 × 10 NOxtrC := 0.0173 + 0.0007⋅ N = 0.025

N2OtrC := 0.000466 + 0.000045⋅ N = 9.61 × 10

−4

−3

PrtrC := 0.00153 + 0.000045⋅ N = 2.025 × 10 SO2trC := 0.0112 + 0.0005⋅ N = 0.0167

Etapa de transport: Dc = 360 NH3tpC := ( 0.000000221 + 0.0003⋅ N) ⋅ Dc = 1.18808 4

CO2tpC := ( 0.039 + 0.0004⋅ N) ⋅ Dc = 15.624 COtpC := ( 0.00322 + 0.0002⋅ N) ⋅ Dc = 1.9512 −7

HCLtpC := ( 0.000000000305 + 0.00000000005 ⋅ N) ⋅ Dc = 3.078 × 10

HFtpC := ( 0.0000000000164 + 0.0000000000003 ⋅ N) ⋅ Dc = 7.092 × 10

−9 −9

H2StpC := ( 0.000000000000154 + 0.0000000000003 ⋅ N) ⋅ Dc = 1.24344 × 10 CH4tpC := ( 0.00000204 + 0.00000006⋅ N) ⋅ Dc = 9.72 × 10

−4

NOxtpC := ( 0.000413 + 0.000007⋅ N) ⋅ Dc = 0.1764 −4

N2OtpC := ( 0.00000055 + 0.0000000138⋅ N) ⋅ Dc = 2.52648 × 10 PrtpC := ( 0.0000412 + 0.00000045⋅ N) ⋅ Dc = 0.016614 SO2tpC := ( 0.000213 + 0.000005⋅ N) ⋅ Dc = 0.09648

Etapa de Combustie: −4

NH3cC := 0.000121 + 0.000008⋅ N = 2.09 × 10 COcC := ( 0.1737 + 0.002⋅ N) = 0.1957

HGcC := ( 0.0000407 + 0.0000003 ⋅ N) = 4.4 × 10

−5 −6

HCLcC := ( 0.00000196 + 0.00000005⋅ N) = 2.51 × 10

−7

HFcC := ( 0.0000001699 + 0.000000003 ⋅ N) = 2.029 × 10

−8

H2ScC := ( 0.00000000989 + 0.00000000003 ⋅ N) = 1.022 × 10 CH4cC := ( 0.00943 + 0.00006 ⋅ N) = 0.01009 N2OcC := ( 0.00353 + 0.000138⋅ N) = 5.048 × 10

−3

FILIERA DE GAZ NATURAL Extractie C6H6exGN := 0.044 + 0.0005⋅ N = 0.0495 CO2exGN := 76.52 + 0.08⋅ N = 77.4 COexGN := 0.0624 + 0.002⋅ N = 0.0844 CH4exGN := 3.801 + 0.02⋅ N = 4.021 NOexGN := 0.372 + 0.007⋅ N = 0.449 −4

N2OexGN := 0.000625 + 0.000018⋅ N = 8.23 × 10 PrexGN := 0.0451 + 0.00075 ⋅ N = 0.05335 SO2exGN := 0.144 + 0.002⋅ N = 0.166

Tratare

C6H6trGN := 0.224 + 0.005⋅ N = 0.279 5

CO2trGN := 22 + 0.4⋅ N = 26.4 COtrGN := 0.0718 + 0.003⋅ N = 0.1048 CH4trGN := 2.82 + 0.08⋅ N = 3.7 NOtrGN := 0.171 + 0.007⋅ N = 0.248 N2OtrGN := 0.00036 + 0.000018⋅ N = 5.58 × 10

−4

PrtrGN := 0.02 + 0.00075 ⋅ N = 0.02825 SO2trGN := 1.02 + 0.002⋅ N = 1.042 Transport −3

C6H6tpGN := ( 0.00000219 + 0.00000005⋅ N) ⋅ Dgn = 5.4115 × 10 CO2tpGN := ( 0.306 + 0.004⋅ N) ⋅ Dgn = 691.25 COtpGN := ( 0.00269 + 0.00003 ⋅ N) ⋅ Dgn = 5.9645 CH4tpGN := ( 0.00724 + 0.00008 ⋅ N) ⋅ Dgn = 16.037 NOxtpGN := ( 0.00245 + 0.00007 ⋅ N) ⋅ Dgn = 6.3595 N2OtpGN := ( 0.00003879 + 0.00000018⋅ N) ⋅ Dgn = 0.080521 PrtpGN := ( 0.00003879 + 0.00000018⋅ N) ⋅ Dgn = 0.080521 SO2tpGN := ( 0.000268 + 0.00002 ⋅ N) ⋅ Dgn = 0.9638

Combustie NH3cGN := 0.137 + 0.004⋅ N = 0.181 C6H6cGN := 0.0496 + 0.0005⋅ N = 0.0551 COcGN := 0.174 + 0.003⋅ N = 0.207 CH2OcGN := 0.056 + 0.0004⋅ N = 0.0604 CH4cGN := 2.212 + 0.09⋅ N = 3.202 Filiera de carbune (Ardere in pat fluidizat circulant)

Combustie COcb := 0.00395 + 0.00002 ⋅ N = 4.17 × 10

−3

HCLcb := 0.00395 + 0.00002 ⋅ N = 4.17 × 10

−3

HFcb := 0.000000117 + 0.000000003 ⋅ N = 1.5 × 10

−7 −9

H2Scb := 0.00000000646 + 0.00000000003 ⋅ N = 6.79 × 10 −4

CH4cb := 0.000269 + 0.000006⋅ N = 3.35 × 10

−4

N2Ocb := 0.000139 + 0.000008⋅ N = 2.27 × 10

6

Recalcularea emisiilor specifice

Filiera de carbune Etapa de extractie 7

Maex = 4.726 × 10

NH3exCrec := NH3exC⋅ Maex = 2.49062 × 10

6

g g

8

CO2exCrec := CO2exC⋅ Maex = 2.13758 × 10 5

COexCrec := COexC⋅ Maex = 2.84035 × 10

g

HCLexCrec := HCLexC⋅ Maex = 0.0879

g

HFexCrec := HFexC⋅ Maex = 0.13044

g

H2SexCrec := H2SexC⋅ Maex = 0.06427

g 7

CH4exCrec := CH4exC⋅ Maex = 3.33233 × 10

NOxexCrec := NOxexC⋅ Maex = 1.26658 × 10

6

N2OexCrec := N2OexC⋅ Maex = 2.21084 × 10

4

PrexCrec := PrexC⋅ Maex = 6.06822 × 10

5

g g g g

SO2exCrec := SO2exC⋅ Maex = 2.98685 × 10

6

g

Etapa de tratare 7

Matr = 4.045483 × 10

g

6

NH3trCrec := ( NH3trC⋅ Matr) = 1.12464 × 10 CO2trCrec := CO2trC⋅ Matr = 1.869 × 10

g

8

COtrCrec := COtrC⋅ Matr = 2.19265 × 10

g

HCLtrCrec := HCLtrC⋅ Matr = 0.14564

g

HFtrCrec := HFtrC⋅ Matr = 0.22614

g

H2StrCrec := H2StrC⋅ Matr = 0.05866

g

5

5

CH4trCrec := CH4trC⋅ Matr = 3.25257 × 10

6

NOxtrCrec := NOxtrC⋅ Matr = 1.01137 × 10

N2OtrCrec := N2OtrC⋅ Matr = 3.88771 × 10

4

g g g

4

PrtrCrec := PrtrC⋅ Matr = 8.1921 × 10

SO2trCrec := SO2trC⋅ Matr = 6.75596 × 10

g

5

g

Etapa de transport:

7

Dc = 360 7

Matp = 3.572162 × 10

10

NH3tpCrec := NH3tpC⋅ Matp ⋅ Dc = 1.52784 × 10 CO2tpCrec := CO2tpC⋅ Dc⋅ Matp = 2.00921 × 10

g g

11

10

COtpCrec := COtpC⋅ Dc⋅ Matp = 2.5092 × 10

g 3

HCLtpCrec := HCLtpC⋅ Dc⋅ Matp = 3.95824 × 10

g

HFtpCrec := HFtpC⋅ Dc⋅ Matp = 91.20158

g

H2StpCrec := H2StpC⋅ Dc⋅ Matp = 15.99037

g

CH4tpCrec := CH4tpC⋅ Dc⋅ Matp = 1.24997 × 10

7

g

9

NOxtpCrec := NOxtpC⋅ Dc⋅ Matp = 2.26847 × 10 N2OtpCrec := N2OtpC⋅ Matp ⋅ Dc = 3.249 × 10

g

6

g g

8

PrtpCrec := ( PrtpC ) ⋅ Dc⋅ Matp = 2.13652 × 10

g

9

SO2tpCrec := SO2tpC⋅ Dc⋅ Matp = 1.24071 × 10

FILIERA DE GAZ NATURAL Extractie Mbex = 1.294 × 10

7

g

5

C6H6exGNrec := C6H6exGN⋅ Mbex = 6.4053 × 10

g

9

CO2exGNrec := CO2exGN⋅ Mbex = 1.00156 × 10

6

COexGNrec := COexGN⋅ Mbex = 1.09214 × 10

g

7

CH4exGNrec := CH4exGN⋅ Mbex = 5.20317 × 10 6

NOexGNrec := NOexGN⋅ Mbex = 5.81006 × 10

g g

4

N2OexGNrec := N2OexGN⋅ Mbex = 1.06496 × 10

g g

5

PrexGNrec := PrexGN⋅ Mbex = 6.90349 × 10

6

SO2exGNrec := SO2exGN⋅ Mbex = 2.14804 × 10

g

Tratare

8

Mbtr = 1.206008 × 10

7

C6H6trGNrec := C6H6trGN⋅ Mbtr = 3.36476 × 10

g

6

g

8

CO2trGNrec := CO2trGN⋅ Mbtr = 3.18386 × 10 6

COtrGNrec := COtrGN⋅ Mbtr = 1.2639 × 10

g 7

CH4trGNrec := CH4trGN⋅ Mbtr = 4.46223 × 10 NOtrGNrec := NOtrGN⋅ Mbtr = 2.9909 × 10

g

6

g 3

N2OtrGNrec := N2OtrGN⋅ Mbtr = 6.72952 × 10

g

5

PrtrGNrec := PrtrGN⋅ Mbtr = 3.40697 × 10

SO2trGNrec := SO2trGN⋅ Mbtr = 1.25666 × 10

g 7

g

Transport Dgn = 1.975 × 10

3 7

Mbtp = 1.087819 × 10

g

8

C6H6tpGNrec := ( 0.00000219 + 0.00000005⋅ N) ⋅ Dgn⋅ Mbtp⋅ Dgn = 1.16263 × 10

g

13

CO2tpGNrec := ( 0.306 + 0.004⋅ N) ⋅ Dgn⋅ Mbtp⋅ Dgn = 1.48511 × 10

11

COtpGNrec := ( 0.00269 + 0.00003 ⋅ N) ⋅ Dgn⋅ Mbtp⋅ Dgn = 1.28144 × 10

g

11

CH4tpGNrec := ( 0.00724 + 0.00008 ⋅ N) ⋅ Dgn⋅ Mbtp⋅ Dgn = 3.44546 × 10

g

11

NOxtpGNrec := ( 0.00245 + 0.00007 ⋅ N) ⋅ Dgn⋅ Mbtp⋅ Dgn = 1.3663 × 10

N2OtpGNrec := ( 0.00003879 + 0.00000018⋅ N) ⋅ Dgn⋅ Mbtp⋅ Dgn = 1.72994 × 10 9

9

g g

PrtpGNrec := ( 0.00003879 + 0.00000018⋅ N) ⋅ Dgn⋅ Mbtp⋅ Dgn = 1.72994 × 10 10

g

SO2tpGNrec := ( 0.000268 + 0.00002 ⋅ N) ⋅ Dgn⋅ Mbtp⋅ Dgn = 2.07067 × 10

Filiera de carbune (Ardere in pat fluidizat circulant) Etapa de extractie 7

Mcex = 4.510697 × 10

6

NH3exCrec3 := NH3exC⋅ Mcex = 2.37714 × 10

g g

8

CO2exCrec3 := CO2exC⋅ Mcex = 2.04019 × 10 COexCrec3 := COexC⋅ Mcex = 2.71093 × 10

5

g

HCLexCrec3 := HCLexC⋅ Mcex = 0.0839

g

HFexCrec3 := HFexC⋅ Mcex = 0.1245

g

H2SexCrec3 := H2SexC⋅ Mcex = 0.06135

g 7

CH4exCrec3 := CH4exC⋅ Mcex = 3.18049 × 10

6

NOxexCrec3 := NOxexC⋅ Mcex = 1.20887 × 10

g g

9

4

N2OexCrec3 := N2OexC⋅ Mcex = 2.1101 × 10

g

5

PrexCrec3 := PrexC⋅ Mcex = 5.79174 × 10

g 6

SO2exCrec3 := SO2exC⋅ Mcex = 2.85076 × 10

g

Etapa de tratare 7

Mctr = 3.861157 × 10

g

6

NH3trCrec3 := ( NH3trC⋅ Mctr) = 1.0734 × 10

g

8

CO2trCrec3 := CO2trC⋅ Mctr = 1.78385 × 10 COtrCrec3 := COtrC⋅ Mctr = 2.09275 × 10

g

5

HCLtrCrec3 := HCLtrC⋅ Mctr = 0.139

g

HFtrCrec3 := HFtrC⋅ Mctr = 0.21584

g

H2StrCrec3 := H2StrC⋅ Mctr = 0.05599

g g

5

CH4trCrec3 := CH4trC⋅ Mctr = 3.10437 × 10

g

5

NOxtrCrec3 := NOxtrC⋅ Mctr = 9.65289 × 10

4

N2OtrCrec3 := N2OtrC⋅ Mctr = 3.71057 × 10

g g

4

PrtrCrec3 := PrtrC⋅ Mctr = 7.81884 × 10

g

5

SO2trCrec3 := SO2trC⋅ Mctr = 6.44813 × 10

Etapa de transport: 7

Mctp = 3.409401 × 10 Dc = 360

NH3tpCrec3 := NH3tpC⋅ Mctp ⋅ Dc = 1.45823 × 10

10

g

11

CO2tpCrec3 := CO2tpC⋅ Dc⋅ Mctp = 1.91767 × 10

g

10

COtpCrec3 := COtpC⋅ Dc⋅ Mctp = 2.39487 × 10

g 3

HCLtpCrec3 := HCLtpC⋅ Dc⋅ Mctp = 3.77789 × 10 HFtpCrec3 := HFtpC⋅ Dc⋅ Mctp = 87.04611

g g

H2StpCrec3 := H2StpC⋅ Dc⋅ Mctp = 15.26179

g 7

CH4tpCrec3 := CH4tpC⋅ Dc⋅ Mctp = 1.19302 × 10

g

NOxtpCrec3 := NOxtpC⋅ Dc⋅ Mctp = 2.16511 × 10

9

N2OtpCrec3 := N2OtpC⋅ Mctp ⋅ Dc = 3.10096 × 10

6

g g

PrtpCrec3 := ( PrtpC ) ⋅ Dc⋅ Mctp = 2.03918 × 10

8

SO2tpCrec3 := SO2tpC⋅ Dc⋅ Mctp = 1.18418 × 10

g 9

g

10

Etapa 3

Emisia de CO2

Filiera de carbune (ardere pulverizata) Bca :=

kg

Mac daf ⋅ 3600

= 1.511508

s

7

Mac = 2.979183 × 10 3

daf = 5.475 × 10

Bco2a := 3.67⋅ c⋅ Bca = 2.340933

Filiera de gaz natural Mch4 := 16

Mc2h6 := 30

Mc := 12

Mco2 := 44

Mc3h8 := 44 Mh2s := 34

Mc4h10 := 58

Mc5h12 := 72

Mh := 1

Mo := 16

Ms := 32

Mam1 := ch4⋅ Mch4 + c2h6⋅ Mc2h6 + c3h8⋅ Mc3h8 + c4h10⋅ Mc3h8 = 16.7284 Mam2 := c5h12⋅ Mc5h12 + co2⋅ Mco2 + h2s⋅ Mh2s = 5.3229

Mam := Mam1 + Mam2 = 22.0513

Gch4 :=

Mch4⋅ ch4 Mam

Mc2h6⋅ c2h6

Gc2h6 :=

Mam Mc3h8⋅ c3h8

Gc3h8 :=

Mam

Gc4h10 :=

Gc5h12 :=

Gco2 :=

Gh2s :=

= 0.583657

= 0.034284

= 0.072431

Mc4h10 ⋅ c4h10 Mam Mc5h12 ⋅ c5h12 Mam

Mco2⋅ co2 Mam Mh2s ⋅ h2s Mam

= 0.089954

= 0.115912

= 0.115191

= 0.010284

11

Ci :=

Hi :=

Oi :=

Si :=

Mc

⋅ Gch4 +

Mch4 Mh⋅ 4 Mch4

Mo⋅ 2 Mco2

Mc2h6 Mh⋅ 6 Mc2h6

⋅ Gc2h6 +

⋅ Gc2h6 +

Mc⋅ 3 Mc3h8 Mh⋅ 8 Mc3h8

⋅ Gc3h8 +

⋅ Gc3h8 +

Mc⋅ 4 Mc4h10 Mh⋅ 10 Mc4h10

⋅ Gc4h10 +

⋅ Gc4h10 +

Mc⋅ 5 Mc5h12 Mh⋅ 12 Mc5h12

⋅ Gc5h12 +

⋅ Gc5h12 +

Mc Mco2 Mh⋅ 2 Mh2s

⋅ Gco2 = 0.726885

⋅ Gh2s = 0.201373

⋅ Gco2 = 0.083776 −3

Ms

⋅ Gh2s = 9.679248 × 10

Mh2s

Bcb :=

⋅ Gch4 +

Mc⋅ 2

Mbc daf ⋅ 3600

6

Mbc = 9.605441 × 10

= 0.487338

3

daf = 5.475 × 10

Bco2b := 3.67⋅ Ci⋅ Bcb = 1.300057

Filiera de carbune(arderea in pat fluidizat) Mcc

Bcc :=

daf ⋅ 3600

= 1.442639

Bco2c := 3.67⋅ c⋅ Bcc = 2.234272

c = 0.422

Calculul emisiilor de NOx (oxid de azot) Combustibili gazosi Filiera de gaz natural β1 := 0.85 β2 := 0.03 β3 := 0.85 D := 70 − 2 ⋅ N = 48

h

t

Dn := 70

k := 3.5⋅

t

h D

Dn

= 2.4

q4 := ( 0.04 − 0.001⋅ N) ⋅ 100 = 2.9 r := 0.25 − 0.005⋅ N = 0.195 Bgn :=

Mbc daf

3

= 1.754419 × 10

3

m

h

12

Bgnn :=

Bgn

3

= 0.487338

3600

m

4

s −6

Bnoxb := 0.034⋅ 10

⋅ β1⋅ k⋅ Bgnn⋅

PCIgn = 4.306928 × 10 PCIgnn 1000

−6

( 1 − 0.01⋅ q4) ( 1 − β2⋅ r) ⋅ β3 = 1.188375 × 10

g s

Combustibili solizi si lichizi Filiera de carbune (ardere pulverizata) Tgt := 1900 − 2.5⋅ N = 1.8725 × 10

3

K

3

Tgo := 1300 − 2.5⋅ N = 1.2725 × 10 Tfl := 0.925⋅ ( Tgt⋅ Tgo)

0.5

K 3

= 1.427847 × 10

K

λf := 1.4

− 64500

λf := 1.4 16

Tfl

0.45⋅ 10 ⋅ e Knoxtermic :=

⋅ 

λf − 1 

  λf 

0.5 −6

= 1.532807 × 10

Tfl n2

Xn :=

−6

= 0.866887

PCIc = 1.926433 × 10

4

PCIc⋅ 10

2

ελ := ( 0.35⋅ λf + 0.4) = 0.7921 p := 0.2 εp := 1.73⋅ p + 0.48 = 0.826 εr := 1 − 0.016⋅ r = 0.992935

r = 0.195

1

εθ := 0.11⋅ ( Tfl − 1100)

3

= 0.758489

kw := 2.4

(

2

)

εw := 0.04⋅ kw + 0.32 = 0.2432 Knoxcombustie := 0.7⋅ Xn⋅ ελ⋅ εp ⋅ εr⋅ εθ⋅ εw = 0.07272 Knox := Knoxtermic + Knoxcombustie = 0.072722

GJ

kg

Bca = 1.511508 Bnoxa := Bca⋅ PCIc⋅

kg

s Knox 1000

= 2.117523

PCIc = 1.926433 × 10

4

13

Filiera de carbune (ardere in pat pulverizat) kg

Bcc = 1.442639

s

Bnoxc := Bcc⋅ PCIc⋅

Knox 1000

= 2.021041

PCIc = 1.926433 × 10

4

Calculul emisiilor de praf

aantr := 0.3 ηd :=

99.5 100 q4 = 2.9

Filiera de carbune (ardere pulverizata) Bprafa := 10( 1 − ηd )  A + q4⋅



 ⋅ aantr⋅ Bca = 0.045496  32700  PCIc

kg

Bca = 1.511508

s

Filiera de carbune (ardere in strat fluidizat)

Bprafc := 10( 1 − ηd )  A + q4⋅



 ⋅ aantr⋅ Bcc = 0.043423  32700  PCIc

kg s

Bcc = 1.442639

Calculul emisiilor de oxizi de sulf

ηcev := 0.2 ηgnev := 0 ηdd := 0 Filiera de carbune (ardere pulverizata)

Bso2a := 20⋅ Bca⋅ s⋅ ( 1 − ηdd ) ( 1 − ηcev) = 0.7618 Filiera de carbune (ardere in pat fluidizat)

Bso2c := 20⋅ Bcc⋅ s⋅ ( 1 − ηdd ) ( 1 − ηcev) = 0.72709

Bcc = 1.442639

Filiera de gaz natural

Bso2b := 20⋅ Bcb⋅ Si⋅ ( 1 − ηdd) ( 1 − ηcev) = 0.075473

14

4. Analiza de impact

Consumul de resurse naturale

Contributia la epuizarea resurselor de gaz natural si carbune sunt prezentate mai jos:

ADP_gn := 0.0187

kg_sb 3

m ADPgn :=

ADP_gn ρgn

ADPb := 0

ADPc := 0.00671

= 0.0186

kg_sb kg

kg_sb kg kg_sb kg

Pentru a determina contributia la epuizarea unei resurse se tine cont de cantitatea de energie maxima primara extrasa. Prin urmare, obtinem: 5

ADPc_gn := ADPgn⋅ Mbex = 2.40731 × 10

kg_sb

5

ADPc_c := ADPc⋅ Maex = 3.171167 × 10

kg_sb 5

ADPc_c3 := ADPc⋅ Mcex = 3.026678 × 10

kg_sb

Schimbari climatice Contributia relativa a gazelor cu efect de sera este prezentat mai jos:

GWPco2 := 1

kgco2 kgco2

GWPn2o := 280 kgco2 kgn2o

GWPch4 := 21

kgco2 kgch4

15

Filiera de gaz natural

Extractie −3

GWPc_co2_ex_gn := CO2exGNrec⋅ GWPco2⋅ 10

6

= 1.001556 × 10

−3

−3

kgco2

3

GWPc_n2o_ex_gn := N2OexGNrec⋅ GWPn2o ⋅ 10 GWPc_ch4_ex_gn := CH4exGNrec⋅ GWPch4⋅ 10

kgco2

= 2.981893 × 10

kgco2

6

= 1.092666 × 10

6

GWPtot_ex_gn := GWPc_co2_ex_gn + GWPc_n2o_ex_gn + GWPc_ch4_ex_gn = 2.097204 × 10

kgco2

Tratare

−3

GWPc_co2_tr_gn := CO2trGNrec⋅ GWPco2⋅ 10

kgco2

5

= 3.18386 × 10

−3

3

GWPc_n2o_tr_gn := N2OtrGNrec⋅ GWPn2o ⋅ 10

= 1.884266 × 10

kgco2

−3

GWPc_ch4_tr_gn := CH4trGNrec⋅ GWPch4⋅ 10

5

= 9.37068 × 10

kgco2 6

GWPtot_tr_gn := GWPc_co2_tr_gn + GWPc_n2o_tr_gn + GWPc_ch4_tr_gn = 1.257338 × 10

kgco2

Transport

GWPc_co2_tp_gn := CO2tpGNrec⋅ GWPco2⋅ 10

−3

−3

GWPc_n2o_tp_gn := N2OtpGNrec⋅ GWPn2o ⋅ 10 GWPc_ch4_tp_gn := CH4tpGNrec⋅ GWPch4⋅ 10

−3

= 1.485111 × 10 8

= 4.843837 × 10 9

= 7.23546 × 10

10

kgco2 kgco2 kgco2 10

GWPtot_tp_gn := GWPc_co2_tp_gn + GWPc_n2o_tp_gn + GWPc_ch4_tp_gn = 2.257095 × 10

kgco2

Combustie 10

CO2coGNrec := ( 2444.44 + 14⋅ N) ⋅ Mbc = 2.495916 × 10

6

COcoGNrec := ( 0.174 + 0.003⋅ N) ⋅ Mbc = 1.988326 × 10

7

CH4coGNrec := ( 2.212 + 0.09⋅ N) ⋅ Mbc = 3.075662 × 10

16

GWPc_co2_co_gn := CO2coGNrec⋅ GWPco2⋅ 10

−3

= 2.495916 × 10

−3

GWPc_CO_co_gn := COcoGNrec⋅ GWPn2o ⋅ 10

GWPc_ch4_co_gn := CH4coGNrec⋅ GWPch4⋅ 10

7

kgco2

5

= 5.567314 × 10

−3

= 6.458891 × 10

kgco2 5

kgco2 7

GWPtot_co_gn := GWPc_co2_co_gn + GWPc_CO_co_gn + GWPc_ch4_co_gn = 2.616178 × 10

kgco2

Rezultate globale filiera de gaz natural 10

GWPtot_gn := GWPtot_ex_gn + GWPtot_tr_gn + GWPtot_tp_gn + GWPtot_co_gn = 2.260047 × 10

kgco2

Filiera de carbune Extractie −3

GWPc_co2_ex_c := CO2exCrec⋅ GWPco2⋅ 10

5

= 2.137584 × 10

−3

3

GWPc_n2o_ex_c := N2OexCrec⋅ GWPn2o ⋅ 10

−3

GWPc_ch4_ex_c := CH4exCrec⋅ GWPch4⋅ 10

kgco2

= 6.190346 × 10

5

= 6.997883 × 10

kgco2 kgco2 5

GWPtot_ex_c := GWPc_co2_ex_c + GWPc_n2o_ex_c + GWPc_ch4_ex_c = 9.19737 × 10

kgco2

Tratare

−3

GWPc_co2_tr_c := CO2trCrec⋅ GWPco2⋅ 10

kg 5 = 1.869013 × co2 10

−3

kg 4 = 1.088559 ×co2 10

−3

kgco2 3 = 6.830394 × 10

GWPc_n2o_tr_c := N2OtrCrec⋅ GWPn2o ⋅ 10 GWPc_ch4_tr_c := CH4trCrec⋅ GWPch4⋅ 10

5

GWPtot_tr_c := GWPc_co2_tr_c + GWPc_n2o_tr_c + GWPc_ch4_tr_c = 2.046173 × 10

kgco2

Transport

−3

GWPc_co2_tp_c := CO2tpCrec⋅ GWPco2⋅ 10

−3

GWPc_n2o_tp_c := N2OtpCrec⋅ GWPn2o ⋅ 10

−3

GWPc_ch4_tp_c := CH4tpCrec⋅ GWPch4⋅ 10

8

= 2.009212 × 10

kgco2 5

= 9.097195 × 10

5

= 2.624939 × 10

kgco2 kgco2 17

8

GWPtot_tp_c := GWPc_co2_tp_c + GWPc_n2o_tp_c + GWPc_ch4_tp_c = 2.020935 × 10

kgco2

Combustie 10

CO2coCrec := ( 1103.187 + 1.5⋅ N) ⋅ Mac = 3.335752 × 10

5

N2OcoCrec := ( 0.00353 + 0.000138⋅ N) ⋅ Mac = 1.503892 × 10 5

CH4coCrec := ( 0.00943 + 0.00006 ⋅ N) ⋅ Mac = 3.005996 × 10

−3

GWPc_co2_co_c := CO2coCrec⋅ GWPco2⋅ 10

kg 7 = 3.335752 ×co2 10

−3

kg 4 = 4.210896 co2 × 10

−3

kg 3 = 6.312591 × co2 10

GWPc_n2o_co_c := N2OcoCrec⋅ GWPn2o ⋅ 10 GWPc_ch4_co_c := CH4coCrec⋅ GWPch4⋅ 10

7

GWPtot_co_c := GWPc_co2_co_c + GWPc_n2o_co_c + GWPc_ch4_co_c = 3.340594 × 10

kgco2

Rezultate globale filiera de carbune (ardere pulverizata) 8

GWPtot_c := GWPtot_ex_c + GWPtot_tr_c + GWPtot_tp_c + GWPtot_co_c = 2.366237 × 10

Filiera de carbune ardere in pat fluidizat Extractie

GWPc_co2_ex_c3 := CO2exCrec3⋅ GWPco2⋅ 10

−3

= 2.040188 × 10

−3

GWPc_n2o_ex_c3 := N2OexCrec3⋅ GWPn2o ⋅ 10 GWPc_ch4_ex_c3 := CH4exCrec3⋅ GWPch4⋅ 10

−3

kgco2

5 3

= 5.908291 × 10

= 6.679034 × 10

5

kgco2 kgco2 5

GWPtot_ex_c3 := GWPc_co2_ex_c + GWPc_n2o_ex_c + GWPc_ch4_ex_c = 9.19737 × 10

kgco2

Tratare

GWPc_co2_tr_c3 := CO2trCrec3 ⋅ GWPco2⋅ 10

−3

= 1.783854 × 10

−3

GWPc_n2o_tr_c3 := N2OtrCrec3⋅ GWPn2o ⋅ 10

5 4

= 1.03896 × 10

kgco2 kgco2

18

GWPc_ch4_tr_c3 := CH4trCrec3 ⋅ GWPch4⋅ 10

−3

= 6.519177 × 10

kgco2

3

5

GWPtot_tr_c3 := GWPc_co2_tr_c + GWPc_n2o_tr_c + GWPc_ch4_tr_c = 2.046173 × 10

kgco2

Transport

GWPc_co2_tp_c3 := CO2tpCrec3⋅ GWPco2⋅ 10

−3

= 1.917666 × 10

−3

GWPc_n2o_tp_c3 := N2OtpCrec3⋅ GWPn2o ⋅ 10 GWPc_ch4_tp_c3 := CH4tpCrec3⋅ GWPch4⋅ 10

−3

kgco2

8 5

= 8.682695 × 10

= 2.505337 × 10

5

kgco2 kgco2

GWPtot_tp_c3 := GWPc_co2_tp_c + GWPc_n2o_tp_c + GWPc_ch4_tp_c = 2.020935 × 10

8

kgco2

Combustie

CO2coCrec3 := ( 1103.187 + 1.5⋅ N) ⋅ Mcc = 3.183764 × 10

10 5

N2OcoCrec3 := ( 0.00353 + 0.000138⋅ N) ⋅ Mcc = 1.435369 × 10

5

CH4coCrec3 := ( 0.00943 + 0.00006 ⋅ N) ⋅ Mcc = 2.869032 × 10

GWPc_co2_co_c3 := CO2coCrec3⋅ GWPco2⋅ 10

−3

= 3.183764 × 10

−3

GWPc_n2o_co_c3 := N2OcoCrec3⋅ GWPn2o ⋅ 10 GWPc_ch4_co_c3 := CH4coCrec3⋅ GWPch4⋅ 10

−3

7

kgco2 4

= 4.019033 × 10

= 6.024967 × 10

3

kgco2 kgco2

GWPtot_co_c3 := GWPc_co2_co_c + GWPc_n2o_co_c + GWPc_ch4_co_c = 3.340594 × 10

7

kgco2

Rezultate globale filiera de carbune (ardere in pat fluidizat) GWPtot_c3 := GWPtot_ex_c3 + GWPtot_tr_c3 + GWPtot_tp_c3 + GWPtot_co_c3 = 2.366237 × 10

8

Toxicitatea umana

Mai jos se prezinta contributia relativa a poluantilor la aceasta clasa de impact:

19

HTP hcl := 0.5

kgdcb

kgdcb

HTP hf := 94

kghf

kghcl

HTP nox := 1.2

kgdcb kgnox

HTP ch2o := 0.83

kgdcb kgch2o

HTP h2s := 0.22

HTP sox := 0.096 kg sox

kgpr

kgdcb

HTP hg := 260

kgh2s kgdcb

kgdcb

HTP pr := 0.82

kgdcb

HTP c6h6 := 1900

kghg

kgdcb kgc6h6

Determinarea contributiei totale la clasa de toxicitate umana tine cont de masa de poluant generata in cadrul etapei ciclului de viata: extractie, tratare, transport si combustie

Filiera de gaz natural Extractie −3

HTP c_c6h6_ex_gn := C6H6exGNrec⋅ HTP c6h6⋅ 10 −3

HTP c_nox_ex_gn := NOexGNrec⋅ HTP nox ⋅ 10 −3

HTP c_pr_ex_gn := PrexGNrec⋅ HTP pr⋅ 10

6

= 1.217007 × 10 3

= 6.97207 × 10

= 566.08604 −3

HTP c_sox_ex_gn := SO2exGNrec⋅ HTP sox⋅ 10

= 206.211789 6

HTP tot_ex_gn := HTP c_c6h6_ex_gn + HTP c_nox_ex_gn + HTP c_pr_ex_gn + HTP c_sox_ex_gn = 1.224751 × 10

Tratare

−3

HTP c_c6h6_tr_gn := C6H6trGNrec⋅ HTP c6h6⋅ 10 −3

HTP c_nox_tr_gn := NOtrGNrec⋅ HTP nox ⋅ 10 −3

HTP c_pr_tr_gn := PrtrGNrec⋅ HTP pr⋅ 10

6

= 6.393047 × 10 3

= 3.589079 × 10

= 279.371684 −3

HTP c_sox_tr_gn := SO2trGNrec⋅ HTP sox⋅ 10

3

= 1.206394 × 10

6

HTP tot_tr_gn := HTP c_c6h6_tr_gn + HTP c_nox_tr_gn + HTP c_pr_tr_gn + HTP c_sox_tr_gn = 6.398122 × 10

Transport −3

HTP c_c6h6_tp_gn := C6H6tpGNrec⋅ HTP c6h6⋅ 10 −3

HTP c_nox_tp_gn := NOxtpGNrec⋅ HTP nox ⋅ 10

8

= 2.208996 × 10 8

= 1.639562 × 10

20

−3

HTP c_pr_tp_gn := PrtpGNrec⋅ HTP pr⋅ 10

6

= 1.418552 × 10 −3

HTP c_sox_tp_gn := SO2tpGNrec⋅ HTP sox⋅ 10

6

= 1.987842 × 10

8

HTP tot_tp_gn := HTP c_c6h6_tp_gn + HTP c_nox_tp_gn + HTP c_pr_tp_gn + HTP c_sox_tp_gn = 3.882623 × 10

Combustie 5

C6H6coGNrec := ( 0.0496 + 0.0005⋅ N) ⋅ Mbc = 5.292598 × 10 6

NOxcoGNrec := ( 0.633 + 0.007⋅ N) ⋅ Mbc = 6.819863 × 10

5

CH2OcoGNrec := ( 0.056 + 0.0004⋅ N) ⋅ Mbc = 5.801687 × 10 6

PrcoGNrec := ( 0.39 + 0.0075⋅ N) ⋅ Mbc = 4.538571 × 10

5

SO2coGNrec := ( 0.0108 + 0.002⋅ N) ⋅ Mbc = 3.150585 × 10

−3

HTP c_c6h6_co_gn := C6H6coGNrec⋅ HTP c6h6⋅ 10 −3

3

HTP c_nox_co_gn := NOxcoGNrec⋅ HTP nox ⋅ 10

= 8.183836 × 10 −3

HTP c_ch2o_co_gn := CH2OcoGNrec⋅ HTP ch2o⋅ 10 −3

HTP c_pr_co_gn := PrcoGNrec⋅ HTP sox⋅ 10

6

= 1.005594 × 10

= 481.539984

= 435.702818

−3

HTP c_sox_co_gn := SO2coGNrec⋅ HTP sox⋅ 10

= 30.245614

HTP tot_co_gn1 := HTP c_c6h6_co_gn + HTP c_nox_co_gn + HTP c_pr_co_gn = 1.014213 × 10

6

HTP tot_co_gn2 := HTP c_sox_co_gn + HTP c_ch2o_co_gn = 511.785597 6

HTP tot_co_gn := HTP tot_co_gn1 + HTP tot_co_gn2 = 1.014725 × 10 Rezultate globale filiera de gaz natural

8

HTP tot_gn := HTP tot_ex_gn + HTP tot_tr_gn + HTP tot_tp_gn + HTP tot_co_gn = 3.968999 × 10

Filiera de carbune - ardere pulverizata Extractie −3

HTP c_hcl_ex_c := HCLexCrec⋅ HTP hcl⋅ 10

−5

= 4.39521 × 10

21

HTP c_hf_ex_c := HFexCrec⋅ HTP hf ⋅ 10

−3

= 0.012261

HTP c_h2s_ex_c := H2SexCrec⋅ HTP h2s⋅ 10

−3

= 1.414029 × 10

−3

HTP c_nox_ex_c := NOxexCrec⋅ HTP nox ⋅ 10 −3

HTP c_pr_ex_c := PrexCrec⋅ HTP pr⋅ 10

−5

3

= 1.519892 × 10

= 497.59444 −3

HTP c_sox_ex_c := SO2exCrec⋅ HTP sox⋅ 10

= 286.737804

HTP tot_ex_c1 := HTP c_hcl_ex_c + HTP c_hf_ex_c + HTP c_h2s_ex_c = 0.012319 3

HTP tot_ex_c2 := HTP c_nox_ex_c + HTP c_pr_ex_c + HTP c_sox_ex_c = 2.304224 × 10 3

HTP tot_ex_c := HTP tot_ex_c1 + HTP tot_ex_c2 = 2.304236 × 10 Tratare

−3

HTP c_hcl_tr_c := HCLtrCrec⋅ HTP hcl⋅ 10 HTP c_hf_tr_c := HFtrCrec⋅ HTP hf ⋅ 10

−3

= 0.021257 −3

HTP c_h2s_tr_c := H2StrCrec ⋅ HTP h2s⋅ 10

HTP c_nox_tr_c := NOxtrCrec⋅ HTP nox ⋅ 10 −3

HTP c_pr_tr_c := PrtrCrec⋅ HTP pr⋅ 10

−5

= 7.28187 × 10

−5

= 1.290509 × 10

−3

= 1.213645 × 10

3

= 67.175249 −3

HTP c_sox_tr_c := SO2trCrec ⋅ HTP sox⋅ 10

= 64.857188

3

HTP tot_tr_c1 := HTP c_hcl_tr_c + HTP c_hf_tr_c + HTP c_h2s_tr_c + HTP c_nox_tr_c = 1.213666 × 10 HTP tot_tr_c2 := HTP c_pr_tr_c + HTP c_sox_tr_c = 132.032437 3

HTP tot_tr_c := HTP tot_tr_c1 + HTP tot_tr_c2 = 1.345699 × 10

Transport

−3

HTP c_hcl_tp_c := HCLtpCrec⋅ HTP hcl⋅ 10 HTP c_hf_tp_c := HFtpCrec⋅ HTP hf ⋅ 10

−3

= 1.97912

= 8.572948 22

HTP c_h2s_tp_c := H2StpCrec⋅ HTP h2s⋅ 10

−3

= 3.517881 × 10

−3

6

HTP c_nox_tp_c := NOxtpCrec⋅ HTP nox ⋅ 10 −3

HTP c_pr_tp_c := PrtpCrec⋅ HTP pr⋅ 10

−3

= 2.722159 × 10 5

= 1.75195 × 10

HTP c_sox_tp_c := SO2tpCrec⋅ HTP sox⋅ 10

−3

= 1.191083 × 10

5

6

HTP tot_tp_c1 := HTP c_hcl_tp_c + HTP c_hf_tp_c + HTP c_h2s_tp_c + HTP c_nox_tp_c = 2.722169 × 10 5

HTP tot_tp_c2 := HTP c_pr_tp_c + HTP c_sox_tp_c = 2.943033 × 10 6

HTP tot_tp_c := HTP tot_tp_c1 + HTP tot_tp_c2 = 3.016473 × 10

Combustie HCLcoCrec := ( 0.00000196 + 0.00000005⋅ N) ⋅ Mac = 74.77749 HFcoCrec := ( 0.0000001699 + 0.000000003 ⋅ N) ⋅ Mac = 6.044762 H2ScoCrec := ( 0.00000000989 + 0.00000000003 ⋅ N) ⋅ Mac = 0.304472 HGcoCrec := ( 0.0000407 + 0.0000003 ⋅ N) ⋅ Mac = 1.31084 × 10 NOxcoCrec := ( 3.4639 + 0.05⋅ N) ⋅ Mac = 1.195814 × 10

3

8

8

PrcoCrec := ( 10.198 + 0.45⋅ N) ⋅ Mac = 4.512866 × 10

8

SO2coCrec := ( 7.2598 + 0.3⋅ N) ⋅ Mac = 3.145958 × 10

−3

HTP c_hcl_co_c := HCLcoCrec⋅ HTP hcl⋅ 10 HTP c_hf_co_c := HFcoCrec⋅ HTP hf ⋅ 10

−3

HTP c_h2s_co_c := H2ScoCrec⋅ HTP h2s⋅ 10 HTP c_hg_co_c := HGcoCrec⋅ HTP hg⋅ 10

−3

= 0.037389

= 0.568208 −3

= 6.698395 × 10

= 340.81852 −3

HTP c_nox_co_c := NOxcoCrec⋅ HTP nox ⋅ 10 −3

HTP c_pr_co_c := PrcoCrec⋅ HTP pr⋅ 10

−5

5

= 1.434977 × 10 5

= 3.70055 × 10

HTP c_sox_co_c := SO2coCrec⋅ HTP sox⋅ 10

−3

= 3.020119 × 10

4

23

5

HTP tot_co_c1 := HTP c_hcl_co_c + HTP c_hf_co_c + HTP c_h2s_co_c + HTP c_nox_co_c = 1.434983 × 10 5

HTP tot_co_c2 := HTP c_hg_co_c + HTP c_pr_co_c + HTP c_sox_co_c = 4.00597 × 10 5

HTP tot_co_c := HTP tot_co_c1 + HTP tot_co_c2 = 5.440954 × 10

Rezultate globale filiera de carbune (ardere pulverizata) 6

HTP tot_c := HTP tot_ex_c + HTP tot_tr_c + HTP tot_tp_c + HTP tot_co_c = 3.564218 × 10

Filiera de carbune - ardere in pat fluidizat Extractie −3

HTP c_hcl_ex_c3 := HCLexCrec3⋅ HTP hcl⋅ 10 −3

HTP c_hf_ex_c3 := HFexCrec3⋅ HTP hf ⋅ 10

HTP c_h2s_ex_c3 := H2SexCrec3⋅ HTP h2s⋅ 10

−5

= 4.194948 × 10

= 0.011703 −3

= 1.349601 × 10

−3

HTP c_nox_ex_c3 := NOxexCrec3⋅ HTP nox ⋅ 10 −3

HTP c_pr_ex_c3 := PrexCrec3⋅ HTP pr⋅ 10

−5

3

= 1.45064 × 10

= 474.922272

HTP c_sox_ex_c3 := SO2exCrec3⋅ HTP sox⋅ 10

−3

= 273.673012

HTP tot_ex_c31 := HTP c_hcl_ex_c3 + HTP c_hf_ex_c3 + HTP c_h2s_ex_c3 + HTP c_nox_ex_c3 = 1.450652 × 10

3

HTP tot_ex_c32 := HTP c_pr_ex_c3 + HTP c_sox_ex_c3 = 748.595284 HTP tot_ex_c3 := HTP tot_ex_c31 + HTP tot_ex_c32 = 2.199247 × 10

3

Tratare

−3

HTP c_hcl_tr_c3 := HCLtrCrec3⋅ HTP hcl⋅ 10 −3

HTP c_hf_tr_c3 := HFtrCrec3 ⋅ HTP hf ⋅ 10

HTP c_h2s_tr_c3 := H2StrCrec3⋅ HTP h2s⋅ 10

−5

= 6.950082 × 10

= 0.020289 −3

= 1.231709 × 10

−3

HTP c_nox_tr_c3 := NOxtrCrec3⋅ HTP nox ⋅ 10 −3

HTP c_pr_tr_c3 := PrtrCrec3 ⋅ HTP pr⋅ 10

−5

3

= 1.158347 × 10

= 64.114507

HTP c_sox_tr_c3 := SO2trCrec3⋅ HTP sox⋅ 10

−3

= 61.902064

HTP tot_tr_c31 := HTP c_hcl_tr_c3 + HTP c_hf_tr_c3 + HTP c_h2s_tr_c3 + HTP c_nox_tr_c3 = 1.158367 × 10

3 24

HTP tot_tr_c32 := HTP c_pr_tr_c3 + HTP c_sox_tr_c3 = 126.016571 3

HTP tot_tr_c3 := HTP tot_tr_c31 + HTP tot_tr_c32 = 1.284384 × 10

Transport −3

HTP c_hcl_tp_c3 := HCLtpCrec3⋅ HTP hcl⋅ 10 −3

HTP c_hf_tp_c3 := HFtpCrec3⋅ HTP hf ⋅ 10

HTP c_h2s_tp_c3 := H2StpCrec3⋅ HTP h2s⋅ 10

= 1.888945

= 8.182334 −3

= 3.357594 × 10

−3

HTP c_nox_tp_c3 := NOxtpCrec3⋅ HTP nox ⋅ 10 −3

HTP c_pr_tp_c3 := PrtpCrec3⋅ HTP pr⋅ 10

−3

6

= 2.598127 × 10 5

= 1.672125 × 10

HTP c_sox_tp_c3 := SO2tpCrec3⋅ HTP sox⋅ 10

−3

= 1.136813 × 10

5

6

HTP tot_tp_c31 := HTP c_hcl_tp_c3 + HTP c_hf_tp_c3 + HTP c_h2s_tp_c3 + HTP c_nox_tp_c3 = 2.598138 × 10 5

HTP tot_tp_c32 := HTP c_pr_tp_c3 + HTP c_sox_tp_c3 = 2.808938 × 10 6

HTP tot_tp_c3 := HTP tot_tp_c31 + HTP tot_tp_c32 = 2.879031 × 10

Combustie

HCLcoCrec3 := ( 0.00000196 + 0.00000005⋅ N) ⋅ Mcc = 71.370362 HFcoCrec3 := ( 0.0000001699 + 0.000000003 ⋅ N) ⋅ Mcc = 5.769341 H2ScoCrec3 := ( 0.00000000989 + 0.00000000003 ⋅ N) ⋅ Mcc = 0.2906 3

HGcoCrec3 := ( 0.0000407 + 0.0000003 ⋅ N) ⋅ Mcc = 1.251114 × 10 8

NOxcoCrec3 := ( 3.4639 + 0.05⋅ N) ⋅ Mcc = 1.141329 × 10 8

PrcoCrec3 := ( 10.198 + 0.45⋅ N) ⋅ Mcc = 4.307244 × 10

8

SO2coCrec3 := ( 7.2598 + 0.3⋅ N) ⋅ Mcc = 3.002617 × 10

−3

HTP c_hcl_co_c3 := HCLcoCrec3⋅ HTP hcl⋅ 10 −3

HTP c_hf_co_c3 := HFcoCrec3⋅ HTP hf ⋅ 10

= 0.035685

= 0.542318 25

HTP c_h2s_co_c3 := H2ScoCrec3⋅ HTP h2s⋅ 10

−3

−3

HTP c_hg_co_c3 := HGcoCrec3⋅ HTP hg⋅ 10

= 6.393192 × 10

= 325.289619 −3

HTP c_nox_co_c3 := NOxcoCrec3⋅ HTP nox ⋅ 10 −3

HTP c_pr_co_c3 := PrcoCrec3⋅ HTP pr⋅ 10

−5

5

= 1.369594 × 10 5

= 3.53194 × 10

HTP c_sox_co_c3 := SO2coCrec3⋅ HTP sox⋅ 10

−3

= 2.882512 × 10

4

HTP tot_co_c31 := HTP c_hcl_co_c3 + HTP c_hf_co_c3 + HTP c_h2s_co_c3 + HTP c_nox_co_c3 = 1.3696 × 10

5

5

HTP tot_co_c32 := HTP c_pr_co_c3 + HTP c_hg_co_c3 + HTP c_sox_co_c3 = 3.823444 × 10 HTP tot_co_c3 := HTP tot_co_c31 + HTP tot_co_c32 = 5.193044 × 10

5

Rezultate globale filiera de carbune (ardere in pat fluidizat)

HTP tot_c3 := HTP tot_ex_c3 + HTP tot_tr_c3 + HTP tot_tp_c3 + HTP tot_co_c3 = 3.401819 × 10

6

Ecotoxicitate In aceasta categorie intra urmatorii indicatori:

a) poluarea asupra panzei de apa freatica - FAETP b) poluarea apei din mari si oceane - MAETP c) poluarea solului - TETP

Mai jos se prezinta contributia relatica a poluantilor la aceasta clasa de impact:

FAETPc6h6 := 0.000084

FAETPch2o := 8.3

FAETPhf := 4.6

FAETPhg := 320

kgdcb kgc6h6 kgdcb

kgch2o kgdcb

MAETPc6h6 := 0.0028

MAETPch2o := 1.6

kgdcb kgc6h6 kgdcb kgch2o

MAETPhf := 41000000

kghf kgdcb kghg

kgdcb MAETPhg := 12000000 kghg

kgdcb kghf

TETPc6h6 := 0.000016

kgdcb kgc6h6

TETPch2o := 0.94

TETPhf := 0.0029

kgdcb kgch2o kgdcb kghf

TETPhg := 28000

kgdcb kghg

26

Filiera de gaz natural

Extractie −3

FAETPc_c6h6_ex_gn := C6H6exGNrec⋅ FAETPc6h6⋅ 10

= 0.053805

FAETPtot_ex_gn := FAETPc_c6h6_ex_gn = 0.053805 −3

MAETPc_c6h6_ex_gn := C6H6exGNrec⋅ MAETPc6h6⋅ 10

= 1.793484

MAETPtot_ex_gn := MAETPc_c6h6_ex_gn = 1.793484 −3

TETPc_c6h6_ex_gn := C6H6exGNrec⋅ TETPc6h6⋅ 10

= 0.010248

TETPtot_ex_gn := TETPc_c6h6_ex_gn = 0.010248

Tratare

FAETPc_c6h6_tr_gn := C6H6trGNrec⋅ FAETPc6h6⋅ 10

−3

= 0.28264

FAETPtot_tr_gn := FAETPc_c6h6_tr_gn = 0.28264 MAETPc_c6h6_tr_gn := C6H6trGNrec⋅ MAETPc6h6⋅ 10

−3

= 9.421332

MAETPtot_tr_gn := MAETPc_c6h6_tr_gn = 9.421332 −3

TETPc_c6h6_tr_gn := C6H6trGNrec⋅ TETPc6h6⋅ 10

= 0.053836

TETPtot_tr_gn := TETPc_c6h6_tr_gn = 0.053836 Transport −3

FAETPc_c6h6_tp_gn := C6H6tpGNrec⋅ FAETPc6h6⋅ 10

= 9.766089

FAETPtot_tp_gn := FAETPc_c6h6_tp_gn = 9.766089 −3

MAETPc_c6h6_tp_gn := C6H6tpGNrec⋅ MAETPc6h6⋅ 10

= 325.536293

MAETPtot_tp_gn := MAETPc_c6h6_tp_gn = 325.536293 −3

TETPc_c6h6_tp_gn := C6H6tpGNrec⋅ TETPc6h6⋅ 10

= 1.860207

TETPtot_tp_gn := TETPc_c6h6_ex_gn = 0.010248

Combustie 27

−3

FAETPc_c6h6_co_gn := C6H6coGNrec⋅ FAETPc6h6⋅ 10

−3

FAETPc_ch2o_co_gn := CH2OcoGNrec⋅ FAETPch2o⋅ 10

= 0.044458 3

= 4.8154 × 10

3

FAETPtot_co_gn := FAETPc_c6h6_co_gn + FAETPc_ch2o_co_gn = 4.815444 × 10 −3

MAETPc_c6h6_co_gn := C6H6coGNrec⋅ MAETPc6h6⋅ 10

−3

MAETPc_ch2o_co_gn := CH2OcoGNrec⋅ MAETPch2o⋅ 10

= 1.481927 = 928.269848

MAETPtot_co_gn := MAETPc_c6h6_co_gn + MAETPc_ch2o_co_gn = 929.751776 −3

−3

TETPc_c6h6_co_gn := C6H6coGNrec⋅ TETPc6h6⋅ 10

= 8.468157 × 10

−3

TETPc_ch2o_co_gn := CH2OcoGNrec⋅ TETPch2o⋅ 10

= 545.358536

TETPtot_co_gn := TETPc_c6h6_co_gn + TETPc_ch2o_co_gn = 545.367004

FAETPtot_gn := FAETPtot_ex_gn + FAETPtot_tr_gn + FAETPtot_tp_gn + FAETPtot_co_gn = 4.825547 × 10

3

MAETPtot_gn := MAETPtot_ex_gn + MAETPtot_tr_gn + MAETPtot_tp_gn + MAETPtot_co_gn = 1.266503 × 10

3

Rezultate globale filiera de gaz natural TETPtot_gn := TETPtot_ex_gn + TETPtot_tr_gn + TETPtot_tp_gn + TETPtot_co_gn = 545.441337

Filiera de carbune - ardere pulverizata

Extractie −3

FAETPc_hf_ex_c := HFexCrec⋅ FAETPhf ⋅ 10

= 6.00017 × 10

−4

−4

FAETPtot_ex_c := FAETPc_hf_ex_c = 6.00017 × 10 −3

MAETPc_hf_ex_c := HFexCrec⋅ MAETPhf ⋅ 10

3

= 5.347978 × 10

MAETPtot_ex_c := MAETPc_hf_ex_c = 5.347978 × 10 TETPc_hf_ex_c := HFexCrec⋅ TETPhf ⋅ 10

−3

3

= 3.782716 × 10

−7

−7

TETPtot_ex_c := TETPc_hf_ex_c = 3.782716 × 10

Tratare

28

−3

FAETPc_hf_tr_c := HFtrCrec⋅ FAETPhf ⋅ 10

−3

= 1.040256 × 10

FAETPtot_tr_c := FAETPc_hf_tr_c = 1.040256 × 10 −3

MAETPc_hf_tr_c := HFtrCrec⋅ MAETPhf ⋅ 10 −3

MAETPtot_tr_c := MAETPc_hf_tr_c⋅ 10 TETPc_hf_tr_c := HFtrCrec⋅ TETPhf ⋅ 10

−3

−3 3

= 9.271843 × 10

= 9.271843 = 6.558133 × 10

−7

−7

TETPtot_tr_c := TETPc_hf_tr_c = 6.558133 × 10

Transport −3

FAETPc_hf_tp_c := HFtpCrec⋅ FAETPhf ⋅ 10

= 0.419527

FAETPtot_tp_c := FAETPc_hf_tp_c = 0.419527 −3

MAETPc_hf_tp_c := HFtpCrec⋅ MAETPhf ⋅ 10

6

= 3.739265 × 10

MAETPtot_tp_c := MAETPc_hf_tp_c = 3.739265 × 10 TETPc_hf_tp_c := HFtpCrec⋅ TETPhf ⋅ 10

−3

6

= 2.644846 × 10

−4

−4

TETPtot_tp_c := TETPc_hf_tp_c = 2.644846 × 10 Combustie −3

FAETPc_hf_co_c := HFcoCrec⋅ FAETPhf ⋅ 10

= 0.027806

−3

FAETPc_hg_co_c := HGcoCrec⋅ FAETPhg⋅ 10

= 419.468948

FAETPtot_co_c := FAETPc_hf_co_c + FAETPc_hg_co_c = 419.496754 −3

MAETPc_hf_co_c := HFcoCrec⋅ MAETPhf ⋅ 10

−3

MAETPc_hg_co_c := HGcoCrec⋅ MAETPhg⋅ 10

5

= 2.478352 × 10

7

= 1.573009 × 10

MAETPtot_co_c := MAETPc_hf_co_c + MAETPc_hg_co_c = 1.597792 × 10 TETPc_hf_co_c := HFcoCrec⋅ TETPhf ⋅ 10

−3

TETPc_hg_co_c := HGcoCrec⋅ TETPhg⋅ 10

−3

= 1.752981 × 10

7

−5

= 3.670353 × 10

4 4

TETPtot_co_c := TETPc_hf_co_c + TETPc_hg_co_c = 3.670353 × 10 Rezultate globale filiera de carbune (ardere pulverizata)

FAETPtot_c := FAETPtot_ex_c + FAETPtot_tr_c + FAETPtot_tp_c + FAETPtot_co_c = 419.917922 29

7

MAETPtot_c := MAETPtot_ex_c + MAETPtot_tr_c + MAETPtot_tp_c + MAETPtot_co_c = 1.972254 × 10 TETPtot_c := TETPtot_ex_c + TETPtot_tr_c + TETPtot_tp_c + TETPtot_co_c = 3.670353 × 10

4

Filiera de carbune - ardere in strat fluidizat

Extractie FAETPc_hf_ex_c3 := HFexCrec3⋅ FAETPhf ⋅ 10

−3

= 5.726781 × 10

−4

−4

FAETPtot_ex_c3 := FAETPc_hf_ex_c3 = 5.726781 × 10 MAETPc_hf_ex_c3 := HFexCrec3⋅ MAETPhf ⋅ 10

−3

= 5.104305 × 10

3

3

MAETPtot_ex_c3 := MAETPc_hf_ex_c3 = 5.104305 × 10 −3

TETPc_hf_ex_c3 := HFexCrec3⋅ TETPhf ⋅ 10

−7

= 3.610362 × 10

TETPtot_ex_c3 := TETPc_hf_ex_c3 = 3.610362 × 10

−7

Tratare FAETPc_hf_tr_c3 := HFtrCrec3 ⋅ FAETPhf ⋅ 10

−3

= 9.928578 × 10

−4

−4

FAETPtot_tr_c3 := FAETPc_hf_tr_c3 = 9.928578 × 10 MAETPc_hf_tr_c3 := HFtrCrec3 ⋅ MAETPhf ⋅ 10

−3

= 8.849385 × 10

3

3

MAETPtot_tr_c3 := MAETPc_hf_tr_c3 = 8.849385 × 10 −3

TETPc_hf_tr_c3 := HFtrCrec3 ⋅ TETPhf ⋅ 10

−7

= 6.259321 × 10 −7

TETPtot_tr_c3 := TETPc_hf_tr_c3 = 6.259321 × 10

Transport

FAETPc_hf_tp_c3 := HFtpCrec3⋅ FAETPhf ⋅ 10

−3

= 0.400412

FAETPtot_tp_c3 := FAETPc_hf_tp_c3 = 0.400412 MAETPc_hf_tp_c3 := HFtpCrec3⋅ MAETPhf ⋅ 10

−3

MAETPtot_tp_c3 := MAETPc_hf_tp_c3 = 3.56889 × 10 −3

TETPc_hf_tp_c3 := HFtpCrec3⋅ TETPhf ⋅ 10

6

= 3.56889 × 10 6 −4

= 2.524337 × 10

30

TETPtot_tp_c3 := TETPc_hf_tp_c3 = 2.524337 × 10

−4

Combustie

FAETPc_hf_co_c3 := HFcoCrec3⋅ FAETPhf ⋅ 10

−3

FAETPc_hg_co_c3 := HGcoCrec3⋅ FAETPhg⋅ 10

= 0.026539

−3

= 400.356454

FAETPtot_co_c3 := FAETPc_hf_co_c3 + FAETPc_hg_co_c3 = 400.382993 MAETPc_hf_co_c3 := HFcoCrec3⋅ MAETPhf ⋅ 10

−3

MAETPc_hg_co_c3 := HGcoCrec3⋅ MAETPhg⋅ 10

−3

5

= 2.36543 × 10

= 1.501337 × 10

7 7

MAETPtot_co_c3 := MAETPc_hf_co_c3 + MAETPc_hg_co_c3 = 1.524991 × 10 −3

TETPc_hf_co_c3 := HFcoCrec3⋅ TETPhf ⋅ 10

−3

TETPc_hg_co_c3 := HGcoCrec3⋅ TETPhg⋅ 10

−5

= 1.673109 × 10

4

= 3.503119 × 10

4

TETPtot_co_c3 := TETPc_hf_co_c3 + TETPc_hg_co_c3 = 3.503119 × 10

Rezultate globale filiera de carbune (ardere in pat fluidizat) FAETPtot_c3 := FAETPtot_ex_c3 + FAETPtot_tr_c3 + FAETPtot_tp_c3 + FAETPtot_co_c3 = 400.784971 7

MAETPtot_c3 := MAETPtot_ex_c3 + MAETPtot_tr_c3 + MAETPtot_tp_c3 + MAETPtot_co_c3 = 1.883275 × 10 4

TETPtot_c3 := TETPtot_ex_c3 + TETPtot_tr_c3 + TETPtot_tp_c3 + TETPtot_co_c3 = 3.503119 × 10

Poluarea fotochimica Indicatorul care sta la baza acestei clase de impact poarta denumirea de potentialul de poluare fotochimica, POCP. Mai jos se prezinta contributia relativa a poluantilor la aceasta clasa de impact:

POCP co := 0.027

POCP ch4 := 0.006

kgc2h4 kgco kgc2h4 kgch4

POCP ch2o := 0.519

kgc2h4 kgch2o

POCP nox := 0.028

kgc2h4 kgno2

31

POCP sox := 0.048

kgc2h4 kgso2

Filiera de gaz natural

Extractie −3

POCP c_co_ex_gn := COexGNrec⋅ POCP co⋅ 10

= 29.487665 −3

POCP c_ch4_ex_gn := CH4exGNrec⋅ POCP ch4⋅ 10

−3

POCP c_nox_ex_gn := NOexGNrec⋅ POCP nox ⋅ 10

= 312.190363

= 162.68164

−3

POCP c_sox_ex_gn := SO2exGNrec⋅ POCP sox⋅ 10

= 103.105895

POCP tot_ex_gn := POCP c_co_ex_gn + POCP c_ch4_ex_gn + POCP c_nox_ex_gn + POCP c_sox_ex_gn = 607.465562

Tratare −3

POCP c_co_tr_gn := COtrGNrec⋅ POCP co⋅ 10

= 34.125194 −3

POCP c_ch4_tr_gn := CH4trGNrec⋅ POCP ch4⋅ 10

−3

POCP c_nox_tr_gn := NOtrGNrec⋅ POCP nox ⋅ 10

−3

POCP c_sox_tr_gn := SO2trGNrec⋅ POCP sox⋅ 10

= 267.73371

= 83.745175 = 603.196813

POCP tot_tr_gn := POCP c_co_tr_gn + POCP c_ch4_tr_gn + POCP c_nox_tr_gn + POCP c_sox_tr_gn = 988.800891 Transport

POCP c_co_tp_gn := COtpGNrec⋅ POCP co⋅ 10

−3

= 3.459884 × 10

POCP c_ch4_tp_gn := CH4tpGNrec⋅ POCP ch4⋅ 10

−3

= 2.067274 × 10

−3

POCP c_nox_tp_gn := NOxtpGNrec⋅ POCP nox ⋅ 10

−3

POCP c_sox_tp_gn := SO2tpGNrec⋅ POCP sox⋅ 10

6

6 6

= 3.825645 × 10 5

= 9.93921 × 10

POCP tot_tp_gn := POCP c_co_tp_gn + POCP c_ch4_tp_gn + POCP c_nox_tp_gn + POCP c_sox_tp_gn = 1.034672 × 10

7

Combustie

POCP c_co_co_gn := COcoGNrec⋅ POCP co⋅ 10

−3

= 53.684811 −3

POCP c_ch2o_co_gn := CH2OcoGNrec⋅ POCP ch2o⋅ 10

= 301.107532

COcoGNrec = 1.988326 32

POCP c_ch4_co_gn := CH4coGNrec⋅ POCP ch4⋅ 10

−3

= 184.539738

−3

POCP c_nox_co_gn := NOxcoGNrec⋅ POCP nox ⋅ 10

−3

POCP c_sox_co_gn := SO2coGNrec⋅ POCP sox⋅ 10

NOxcoGNrec = 6.819863

= 190.956173

= 15.122807

POCP tot_co_gn1 := POCP c_co_co_gn + POCP c_ch4_co_gn + POCP c_nox_co_gn = 429.180723 POCP tot_co_gn2 := POCP c_sox_co_gn + POCP c_ch2o_co_gn = 316.230339 POCP tot_co_gn := POCP tot_co_gn1 + POCP tot_co_gn2 = 745.411062 Rezultate globale filiera de gaz natural 7

POCP tot_gn := POCP tot_ex_gn + POCP tot_tr_gn + POCP tot_tp_gn + POCP tot_co_gn = 1.034907 × 10

Filiera de carbune - ardere pulverizata

Extractie −3

POCP c_co_ex_c := COexCrec⋅ POCP co⋅ 10

= 7.668932 −3

POCP c_ch4_ex_c := CH4exCrec⋅ POCP ch4⋅ 10

= 199.939503

−3

POCP c_nox_ex_c := NOxexCrec⋅ POCP nox ⋅ 10

−3

POCP c_sox_ex_c := SO2exCrec⋅ POCP sox⋅ 10

= 35.464143

= 143.368902

POCP tot_ex_c := POCP c_co_ex_c + POCP c_ch4_ex_c + POCP c_nox_ex_c + POCP c_sox_ex_c = 386.44148 Tratare

−3

POCP c_co_tr_c := COtrCrec⋅ POCP co⋅ 10

POCP c_ch4_tr_ := CH4trCrec⋅ POCP ch4⋅ 10

= 5.92016

−3

POCP c_nox_tr_c := NOxtrCrec⋅ POCP nox ⋅ 10

−3

−3

POCP c_sox_tr_c := SO2trCrec ⋅ POCP sox⋅ 10

= 1.951541 = 28.318383

= 32.428594

POCP tot_tr_c := POCP c_co_tr_c + POCP c_ch4_tr_ + POCP c_nox_tr_c + POCP c_sox_tr_c = 68.618678

Transport

33

−3

5

POCP c_co_tp_c := COtpCrec⋅ POCP co⋅ 10

= 6.774842 × 10

−3

POCP c_ch4_tp_ := CH4tpCrec⋅ POCP ch4⋅ 10

= 74.99825

−3

4

POCP c_nox_tp_c := NOxtpCrec⋅ POCP nox ⋅ 10 POCP c_sox_tp_c := SO2tpCrec⋅ POCP sox⋅ 10

−3

= 6.351704 × 10

= 5.955417 × 10

4

5

POCP tot_tp_c := POCP c_co_tp_c + POCP c_ch4_tp_ + POCP c_nox_tp_c + POCP c_sox_tp_c = 8.006304 × 10

Combustie 6

COcoCrec := ( 0.1737 + 0.002⋅ N) ⋅ Mac = 5.830261 × 10 −3

POCP c_co_co_c := COcoCrec⋅ POCP co⋅ 10

= 157.417044

5

CH4coCrec = 3.005996 × 10 −3

POCP c_ch4_co_ := CH4coCrec⋅ POCP ch4⋅ 10

= 1.803597

−3

3

POCP c_nox_co_c := NOxcoCrec⋅ POCP nox ⋅ 10 POCP c_sox_co_c := SO2coCrec⋅ POCP sox⋅ 10

−3

NOxcoCrec = 1.195814 × 10

= 3.34828 × 10

8

8

SO2coCrec = 3.145958 × 10

4

= 1.51006 × 10

4

POCP tot_co_c := POCP c_co_co_c + POCP c_ch4_co_ + POCP c_nox_co_c + POCP c_sox_co_c = 1.86081 × 10 Rezultate globale filiera de carbune (ardere pulverizata) 5

POCP tot_c := POCP tot_ex_c + POCP tot_tr_c + POCP tot_tp_c + POCP tot_co_c = 8.196935 × 10

Filiera de carbune - ardere in pat fluidizat

Extractie −3

POCP c_co_ex_c3 := COexCrec3⋅ POCP co⋅ 10

= 7.319508

POCP c_ch4_ex_c3 := CH4exCrec3⋅ POCP ch4⋅ 10

−3

= 190.82955

−3

POCP c_nox_ex_c3 := NOxexCrec3⋅ POCP nox ⋅ 10 POCP c_sox_ex_c3 := SO2exCrec3⋅ POCP sox⋅ 10

−3

= 33.848271

= 136.836506

POCP tot_ex_c3 := POCP c_co_ex_c3 + POCP c_ch4_ex_c3 + POCP c_nox_ex_c3 + POCP c_sox_ex_c3 = 368.833834 Tratare 34

−3

POCP c_co_tr_c3 := COtrCrec3⋅ POCP co⋅ 10

= 5.650417

POCP c_ch4_tr_c3 := CH4trCrec3 ⋅ POCP ch4⋅ 10

−3

= 1.862622

−3

POCP c_nox_tr_c3 := NOxtrCrec3⋅ POCP nox ⋅ 10 POCP c_sox_tr_c3 := SO2trCrec3⋅ POCP sox⋅ 10

−3

= 27.028097

= 30.951032

POCP tot_tr_c3 := POCP c_co_tr_c3 + POCP c_ch4_tr_c3 + POCP c_nox_tr_c3 + POCP c_sox_tr_c3 = 65.492167

Transport

−3

POCP c_co_tp_c3 := COtpCrec3⋅ POCP co⋅ 10

5

= 6.466156 × 10

POCP c_ch4_tp_c3 := CH4tpCrec3⋅ POCP ch4⋅ 10

−3

= 71.581063

−3

POCP c_nox_tp_c3 := NOxtpCrec3⋅ POCP nox ⋅ 10 POCP c_sox_tp_c3 := SO2tpCrec3⋅ POCP sox⋅ 10

−3

4

= 6.062297 × 10

= 5.684067 × 10

4

5

POCP tot_tp_c3 := POCP c_co_tp_c3 + POCP c_ch4_tp_c3 + POCP c_nox_tp_c3 + POCP c_sox_tp_c3 = 7.641508 × 10

Combustie 6

COcoCrec3 := ( 0.1737 + 0.002⋅ N) ⋅ Mcc = 5.564613 × 10

−3

POCP c_co_co_c3 := COcoCrec3⋅ POCP co⋅ 10

= 150.244564

POCP c_ch4_co_c3 := CH4coCrec3⋅ POCP ch4⋅ 10

−3

= 1.721419

−3

POCP c_nox_co_c3 := NOxcoCrec3⋅ POCP nox ⋅ 10 POCP c_sox_co_c3 := SO2coCrec3⋅ POCP sox⋅ 10

−3

= 3.19572 × 10

3

= 1.441256 × 10

4

4

POCP tot_co_c3 := POCP c_co_co_c3 + POCP c_ch4_co_c3 + POCP c_nox_co_c3 + POCP c_sox_co_c3 = 1.776025 × 10 Rezultate globale filiera de carbune (ardere in pat fluidizat) POCP tot_c3 := POCP tot_ex_c3 + POCP tot_tr_c3 + POCP tot_tp_c3 + POCP tot_co_c3 = 7.823454 × 10

5

35

Acidificare

Indicatorul care sta la baza acestei clase de impact poarta denumirea de potential de acidificare, AP. Mai jos se prezinta contributia relativa a poluantilor la aceasta clasa de impact:

APnh3 := 1.6

kgso2

kgso2

APnox := 0.5

kgno2

kgnh3

APsox := 1.2

kgso2 kgso2

Filiera de gaz natural Extractie −3

3

APc_nox_ex_gn := NOexGNrec⋅ APnox ⋅ 10

= 2.905029 × 10

−3

3

APc_sox_ex_gn := SO2exGNrec⋅ APsox⋅ 10

= 2.577647 × 10

3

APtot_ex_gn := APc_nox_ex_gn + APc_sox_ex_gn = 5.482677 × 10 Tratare −3

APc_nox_tr_gn := NOtrGNrec⋅ APnox ⋅ 10

−3

APc_sox_tr_gn := SO2trGNrec⋅ AP sox⋅ 10

3

= 1.49545 × 10

4

= 1.507992 × 10

4

APtot_tr_gn := APc_nox_tr_gn + APc_sox_tr_gn = 1.657537 × 10

Transport

−3

APc_nox_tp_gn := NOxtpGNrec⋅ APnox ⋅ 10

−3

APc_sox_tp_gn := SO2tpGNrec⋅ APsox⋅ 10

= 6.83151 × 10

7 7

= 2.484803 × 10

7

APtot_tp_gn := APc_nox_tp_gn + APc_sox_tp_gn = 9.316312 × 10

Combustie 6

NH3coGNrec := ( 0.137 + 0.004⋅ N) ⋅ Mbc = 1.738585 × 10

−3

APc_nh3_co_gn := NH3coGNrec⋅ APnh3 ⋅ 10

3

= 2.781736 × 10

36

−3

APc_nox_co_gn := NOxcoGNrec⋅ APnox ⋅ 10

−3

APc_sox_co_gn := SO2coGNrec⋅ APsox⋅ 10

3

= 3.409932 × 10

6

NOxcoGNrec = 6.819863 × 10 SO2coGNrec = 3.150585 × 10

5

= 378.07017 3

APtot_co_gn := APc_nox_co_gn + APc_sox_co_gn + AP c_nh3_co_gn = 6.569738 × 10

7

APtot_gn := AP tot_ex_gn + APtot_tr_gn + APtot_tp_gn + APtot_co_gn = 9.319175 × 10

Filiera de carbune - Ardere pulverizata Extractie −3

APc_nh3_ex_c := NH3exCrec⋅ AP nh3 ⋅ 10

−3

APc_nox_ex_c := NOxexCrec⋅ AP nox ⋅ 10

−3

3

= 3.98499 × 10 = 633.288267

3

APc_sox_ex_c := SO2exCrec⋅ AP sox⋅ 10

= 3.584223 × 10

3

APtot_ex_c := AP c_nh3_ex_c + AP c_nox_ex_c + AP c_sox_ex_c = 8.202501 × 10

Tratare −3

3

APc_nh3_tr_c := NH3trCrec⋅ AP nh3 ⋅ 10 APc_nox_tr_c := NOxtrCrec⋅ APnox ⋅ 10

−3

−3

APc_sox_tr_c := SO2trCrec ⋅ AP sox⋅ 10

= 1.799431 × 10 = 505.685407

= 810.714844 3

APtot_tr_c := AP c_nh3_tr_c + AP c_nox_tr_c + AP c_sox_tr_c = 3.115831 × 10

Transport

−3

APc_nh3_tp_c := NH3tpCrec⋅ AP nh3 ⋅ 10

−3

APc_nox_tp_c := NOxtpCrec⋅ AP nox ⋅ 10 APc_sox_tp_c := SO2tpCrec⋅ APsox⋅ 10

−3

7

= 2.444551 × 10

6

= 1.134233 × 10

= 1.488854 × 10

6

APtot_tp_c := APc_nh3_tp_c + AP c_nox_tp_c + APc_sox_tp_c = 2.70686 × 10

7

Combustie 3

NH3coCrec := ( 0.000121 + 0.000008⋅ N) ⋅ Mac = 6.226492 × 10

37

−3

APc_nh3_co_c := NH3coCrec⋅ AP nh3 ⋅ 10

= 9.962388

−3

4

APc_nox_co_c := NOxcoCrec⋅ AP nox ⋅ 10 APc_sox_co_c := SO2coCrec⋅ APsox⋅ 10

= 5.979071 × 10

NH3coCrec = 6.226492 × 10

3

NOxcoCrec = 1.195814 × 10

8 8

−3

= 3.775149 × 10

SO2coCrec = 3.145958 × 10

5

5

APtot_co_c := AP c_nh3_co_c + AP c_nox_co_c + AP c_sox_co_c = 4.373156 × 10 Rezultate globale filiera de carbune (ardere pulverizata) 7

APtot_c := APtot_ex_c + APtot_tr_c + APtot_tp_c + APtot_co_c = 2.751723 × 10

Filiera de carbune - Ardere in pat fluidizat

Extractie −3

APc_nh3_ex_c3 := NH3exCrec3⋅ APnh3 ⋅ 10

−3

APc_nox_ex_c3 := NOxexCrec3⋅ AP nox ⋅ 10 APc_sox_ex_c3 := SO2exCrec3⋅ APsox⋅ 10

−3

= 3.80342 × 10

3

= 604.433406

= 3.420913 × 10

3

APtot_ex_c3 := APc_nh3_ex_c3 + APc_nox_ex_c3 + AP c_sox_ex_c3 = 7.828766 × 10

3

Tratare −3

APc_nh3_tr_c3 := NH3trCrec3⋅ AP nh3 ⋅ 10

−3

APc_nox_tr_c3 := NOxtrCrec3⋅ AP nox ⋅ 10 APc_sox_tr_c3 := SO2trCrec3⋅ APsox⋅ 10

−3

3

= 1.717442 × 10 = 482.644585

= 773.775799 3

APtot_tr_c3 := APc_nh3_tr_c3 + AP c_nox_tr_c3 + APc_sox_tr_c3 = 2.973863 × 10

Transport

38

−3

APc_nh3_tp_c3 := NH3tpCrec3⋅ APnh3 ⋅ 10

−3

APc_nox_tp_c3 := NOxtpCrec3⋅ APnox ⋅ 10 APc_sox_tp_c3 := SO2tpCrec3⋅ APsox⋅ 10

−3

7

= 2.333169 × 10

6

= 1.082553 × 10

= 1.421017 × 10

6 7

APtot_tp_c3 := APc_nh3_tp_c3 + APc_nox_tp_c3 + APc_sox_tp_c3 = 2.583526 × 10

Combustie

3

NH3coCrec3 := ( 0.000121 + 0.000008⋅ N) ⋅ Mcc = 5.942791 × 10

−3

APc_nh3_co_c3 := NH3coCrec3⋅ APnh3 ⋅ 10

−3

APc_nox_co_c3 := NOxcoCrec3⋅ APnox ⋅ 10 APc_sox_co_c3 := SO2coCrec3⋅ APsox⋅ 10

−3

= 9.508466 4

= 5.706643 × 10 5

= 3.60314 × 10

8

NOxcoCrec3 = 1.141329 × 10 SO2coCrec3 = 3.002617 × 10

8

5

APtot_co_c3 := APc_nh3_co_c3 + APc_nox_co_c3 + APc_sox_co_c3 = 4.173899 × 10

APtot_c3 := AP tot_ex_c3 + APtot_tr_c3 + APtot_tp_c3 + AP tot_co_c3 = 2.626345 × 10

7

Eutrofizare

EPnh3 := 0.35

kgpo43 kgnh3

EPnox := 0.13

kgpo43 kgno2

Filiera de gaz natural

39

Extractie −3

EPc_nox_ex_gn := NOxexCrec3⋅ EPnox ⋅ 10

= 157.152685

EPtot_ex_gn := EPc_nox_ex_gn = 157.152685

Tratare −3

EPc_nox_tr_gn := NOxtrCrec3⋅ EPnox ⋅ 10

= 125.487592

EPtot_tr_gn := EPc_nox_tr_gn = 125.487592 Transport −3

EPc_nox_tp_gn := NOxtpCrec3⋅ EPnox ⋅ 10

5

= 2.814638 × 10 5

EPtot_tp_gn := EPc_nox_tp_gn = 2.814638 × 10

Combustie EPc_nh3_co_gn := NH3coCrec⋅ EPnh3 ⋅ 10 EPc_nox_co_gn := NOxcoCrec⋅ EPnox ⋅ 10

−3 −3

= 2.179272 = 1.554558 × 10

4

4

EPtot_co_gn := EPc_nox_co_gn + EPc_nh3_co_gn = 1.554776 × 10

5

EPtot_gn := EPtot_ex_gn + EPtot_tr_gn + EPtot_tp_gn + EPtot_co_gn = 2.972942 × 10

Filiera de carbune - Ardere pulverizata

Extractie

−3

EPc_nh3_ex_c := NH3exCrec⋅ EPnox ⋅ 10

−3

EPc_nox_ex_c := NOxexCrec⋅ EPnox ⋅ 10

= 323.780441 = 164.654949

EPtot_ex_c := EPc_nh3_ex_c + EPc_nox_ex_c = 488.435391

40

Tratare

−3

EPc_nh3_tr_c := NH3trCrec⋅ EPnox ⋅ 10 EPc_nox_tr_c := NOxtrCrec⋅ EPnox ⋅ 10

−3

= 146.203765 = 131.478206

EPtot_tr_c := EPc_nh3_tr_c + EPc_nox_tr_c = 277.681971

Transport

−3

EPc_nh3_tp_c := NH3tpCrec⋅ EPnox ⋅ 10

−3

EPc_nox_tp_c := NOxtpCrec⋅ EPnox ⋅ 10

6

= 1.986198 × 10

5

= 2.949005 × 10

6

EPtot_tp_c := EPc_nh3_tp_c + EPc_nox_tp_c = 2.281098 × 10

Combustie −3

EPc_nh3_co_c := NH3coCrec⋅ EPnox ⋅ 10

−3

EPc_nox_co_c := NOxcoCrec⋅ EPnox ⋅ 10

= 0.809444 4

= 1.554558 × 10

4

EPtot_co_c := EPc_nh3_co_c + EPc_nox_co_c = 1.554639 × 10

EPtot_c := EPtot_ex_c + EPtot_tr_c + EPtot_tp_c + EPtot_co_c = 2.297411 × 10

6

Filiera de carbune - Ardere in pat fluidizat

Extractie

−3

EPc_nh3_ex_c3 := NH3exCrec3⋅ EPnox ⋅ 10

−3

EPc_nox_ex_c3 := NOxexCrec3⋅ EPnox ⋅ 10

= 309.027855 = 157.152685

EPtot_ex_c3 := EPc_nh3_ex_c3 + EPc_nox_ex_c3 = 466.180541

41

Tratare

−3

EPc_nh3_tr_c3 := NH3trCrec3⋅ EPnox ⋅ 10

−3

EPc_nox_tr_c3 := NOxtrCrec3⋅ EPnox ⋅ 10

= 139.542202 = 125.487592

EPtot_tr_c3 := EPc_nh3_tr_c3 + EPc_nox_tr_c3 = 265.029795

Transport

−3

EPc_nh3_tp_c3 := NH3tpCrec3⋅ EPnox ⋅ 10

−3

EPc_nox_tp_c3 := NOxtpCrec3⋅ EPnox ⋅ 10

6

= 1.8957 × 10

5

= 2.814638 × 10

EPtot_tp_c3 := EPc_nh3_tp_c3 + EPc_nox_tp_c3 = 2.177163 × 10

6

Combustie −3

EPc_nh3_co_c3 := NH3coCrec3⋅ EPnox ⋅ 10

−3

EPc_nox_co_c3 := NOxcoCrec3⋅ EPnox ⋅ 10

= 0.772563 4

= 1.483727 × 10

4

EPtot_co_c3 := EPc_nh3_co_c3 + EPc_nox_co_c3 = 1.483805 × 10

6

EPtot_c3 := EPtot_ex_c3 + EPtot_tr_c3 + EPtot_tp_c3 + EPtot_co_c3 = 2.192733 × 10

ETAPA 5

Matricea ce contine indicatorii calculati anterior

42

 GWPtot_c ADPc_c POCPtot_c APtot_c EPtot_c HTPtot_c    AW :=  GWPtot_gn ADPc_gn POCP tot_gn APtot_gn EPtot_gn HTP tot_gn   GWP  tot_c3 ADPc_c3 POCP tot_c3 APtot_c3 EPtot_c3 HTP tot_c3    2.366237 × 108 3.171167 × 105 8.196935 × 105 2.751723 × 107 2.297411 × 106 3.564218 × 106     AW = 2.260047 × 1010 2.40731 × 105 1.034907 × 107 9.319175 × 107 2.972942 × 105 3.968999 × 108     2.366237 × 108 3.026678 × 105 7.823454 × 105 2.626345 × 107 2.192733 × 106 3.401819 × 106    GWP := GWPtot_c 0

GWP := GWPtot_gn 1

GWP := GWPtot_c3 2

ADP := ADPc_c 0

ADP := ADPc_gn 1

ADP := ADPc_c3 2

POCP := POCP tot_c 0

POCP := POCP tot_gn 1

POCP := POCP tot_c3 2

AP := APtot_c

AP := APtot_gn

AP := APtot_c3

EP := EPtot_c 0

EP := EPtot_gn 1

EP := EPtot_c3 2

HTP := HTP tot_c

HTP := HTP tot_gn

HTP := HTP tot_c3

0

1

0

GWPmax :=

2

1

2

GWPmin :=

r←0

for i ∈ 0 , 1 , 2

for i ∈ 0 , 1 , 2 r ← GWP if r < GWP i

r ← GWP if r > GWP i

i

10

8

GWPmax = 2.260047 × 10

GWPmin = 2.366237 × 10

ADPmin :=

r←0

20

r ← 10

for i ∈ 0 , 1 , 2

for i ∈ 0 , 1 , 2 r ← ADP if r < ADP i

r ← ADP if r > ADP i

i

i

return r

return r

5

ADPmin = 2.40731 × 10

5

ADPmax = 3.171167 × 10

POCP max :=

i

return r

return r

ADPmax :=

20

r ← 10

POCP min :=

r←0

for i ∈ 0 , 1 , 2

for i ∈ 0 , 1 , 2 r ← POCP if r < POCP i

20

r ← 10

r ← POCP if r > POCP i

i

i

return r

return r 7

POCP max = 1.034907 × 10

5

POCP min = 7.823454 × 10

43

APmax :=

APmin :=

r←0

for i ∈ 0 , 1 , 2

for i ∈ 0 , 1 , 2 r ← AP if r < AP i

r ← AP if r > AP i

i

7

APmin = 2.626345 × 10

7

APmax = 9.319175 × 10

EPmin :=

r←0

i

i

5

EPmin = 2.972942 × 10

6

EPmax = 2.297411 × 10

HTP min :=

r←0 r ← HTP if r < HTP i

r ← HTP if r > HTP i

i

6

HTP min = 3.401819 × 10

8

HTP max = 3.968999 × 10

GWP

0

GWPmax

= 0.98953

GWPn1 := 1 −

ADPmax

=0

0

POCP max

AP APn0 := 1 −

0

AP max

HTP

ADPn1 := 1 −

POCP n1 := 1 −

HTP max

APn1 := 1 −

= 0.240876

ADPmax

1

POCP max

AP = 0.7

0

GWPn2 := 1 −

1

AP max

GWPmax

HTP HTP n1 := 1 −

ADPn2 := 1 −

2

ADPmax POCP

=0

POCP n2 := 1 −

1

HTP max

= 0.98953

APn2 := 1 −

2

AP max

2

= 0.924404

= 0.718178

EP 2 EPn2 := 1 − = 0.045564 EPmax HTP

=0

= 0.045564

POCP max

AP =0

EP 1 EPn1 := 1 − = 0.870596 EPmax

= 0.99102

2

ADP

1

POCP = 0.920795

EP 0 EPn0 := 1 − =0 EPmax

HTP n0 := 1 −

=0

ADP

0

POCP

GWP

1

GWPmax

ADP

POCP n0 := 1 −

i

return r

return r

GWP

20

r ← 10

for i ∈ 0 , 1 , 2

for i ∈ 0 , 1 , 2

ADPn0 := 1 −

i

return r

return r

GWPn0 := 1 −

20

r ← EP if r > EP

r ← EP if r < EP i

r ← 10

for i ∈ 0 , 1 , 2

for i ∈ 0 , 1 , 2

HTP max :=

i

return r

return r

EPmax :=

20

r ← 10

HTP n2 := 1 −

2

HTP max

= 0.991429

44

δ = valoarea maxima - valoarea minima a aceluiasi criteriu

GWP := GWPn0 5

GWP := GWPn1 6

GWP := GWPn2 7

ADP := ADPn0 5

ADP := ADPn1 6

ADP := ADPn2 7

POCP := POCP n0 5

POCP := POCP n1 6

POCP := POCP n2 7

AP := APn0 5

AP := APn1 6

AP := APn2 7

EP := EPn0 5

EP := EPn1 6

EP := EPn2 7

HTP := HTP n0 5

HTP := HTP n1 6

HTP := HTP n2 7

δGWP :=

δAP :=

r←0

r←0 for i ∈ 5 , 6 , 7

for i ∈ 5 , 6 , 7

r ← AP if r < AP

r ← GWP if r < GWP i

i

i

i

return r

return r δAP = 0.72

δGWP = 0.99

δADP :=

δEP :=

r←0

for i ∈ 5 , 6 , 7

for i ∈ 5 , 6 , 7 r ← ADP if r < ADP i

r ← EP if r < EP i

i

i

return r

return r δADP = 0.24

δPOCP :=

r←0

δEP = 0.87 δHTP :=

r←0

r←0 for i ∈ 5 , 6 , 7

for i ∈ 5 , 6 , 7 r ← POCP if r < POCP i

r ← HTP if r < HTP i

i

i

return r

return r δPOCP = 0.92

δHTP = 0.99

 GWPn0 ADPn0 POCPn0 APn0 EPn0 HTPn0    AW n :=  GWPn1 ADPn1 POCP n1 APn1 EPn1 HTP n1   GWP ADP POCP AP EP HTP  n2  n2 n2 n2 n2 n2 

45

 0.99 0 0.92 0.7 0 0.99  AW n =  0 0.24 0 0 0.87 0     0.99 0.05 0.92 0.72 0.05 0.99 

GWP

ADP

POCP

AP

EP

HTP

F1

GWPn0 = 0.98953 ADPn0 = 0

F2

GWPn1 = 0

F3

GWPn2 = 0.98953 ADPn2 = 0.045564 POCP n2 = 0.924404 APn2 = 0.718178 EPn2 = 0.045564 HTP n2 = 0.991429

P

5 δ

δGWP = 0.99

POCP n0 = 0.920795 APn0 = 0.704725 EPn0 = 0

ADPn1 = 0.240876 POCP n1 = 0

4 δADP = 0.24

APn1 = 0

HTP n0 = 0.99102

EPn1 = 0.870596 HTP n1 = 0

3

2

1

4

δPOCP = 0.92

δAP = 0.718

δEP = 0.871

δHTP = 0.991

Calculul matricii de concordanta In prima faza indicele de concordanta se va calcula pentru a calcula matricea de concordanta: Cik=[P+(ai,ak) + P=(ai,ak)]/PT P+(ai,ak) - suma ponderilor criteriilor pentru care actiunea ai, este mai buna decat actiunea ak P=(ai,ak) - suma ponderilor criteriilor pentru care cele doua actiuni sunt echivalente P==0

P-(ai,ak) - suma ponderilor criteriilor pentru care actiunea ak este mai buna decat actiunea ai

PT(ai,ak)=P+(ai,ak)+P-(ai,ak)+P=(ai,ak) -->> PT Pentru calculul de concordanta ne uitam in matricea indicatorilor PT := 5 + 4 + 3 + 2 + 1 + 4 = 19 Calculul indicilor de concordanta: 1. C12 (F1,F2 ) Calculam P+---->notat: Pplus

46

Pplus1 :=

r←0

Pegal1 :=

r←0

r ← r + 5 if GWPn0 > GWPn1

r ← r + 5 if GWPn0 = GWPn1

r ← r + 4 if ADPn0 > ADPn1

r ← r + 4 if ADPn0 = ADPn1

r ← r + 3 if POCP n0 > POCP n1

r ← r + 3 if POCP n0 = POCP n1

r ← r + 2 if APn0 > AP n1

r ← r + 2 if APn0 = AP n1

r ← r + 1 if EPn0 > EPn1

r ← r + 1 if EPn0 = EPn1

r ← r + 4 if HTP n0 > HTP n1

r ← r + 4 if HTP n0 = HTP n1

return r

return r

Pplus1 = 14

Pegal1 = 0 Pplus1 + Pegal1

C12 :=

PT

= 0.736842

2. C13 (F1,F3 ) Calculam P+---->notat: Pplus Pplus2 :=

r←0

Pegal2 :=

r←0

r ← r + 5 if GWPn0 > GWPn2

r ← r + 5 if GWPn2 = GWPn2

r ← r + 4 if ADPn0 > ADPn2

r ← r + 4 if ADPn0 = ADPn2

r ← r + 3 if POCP n0 > POCP n2

r ← r + 3 if POCP n0 = POCP n2

r ← r + 2 if APn0 > AP n2

r ← r + 2 if APn0 = AP n2

r ← r + 1 if EPn0 > EPn2

r ← r + 1 if EPn0 = EPn2

r ← r + 4 if HTP n0 > HTP n2

r ← r + 4 if HTP n0 = HTP n2

return r

return r

Pplus2 = 0 C13 :=

Pegal2 = 5 Pplus2 + Pegal2 PT

= 0.263158

3. C12 (F2,F1 ) Calculam P+---->notat: Pplus Pplus3 :=

r←0

Pegal3 :=

r←0

r ← r + 5 if GWPn1 > GWPn0

r ← r + 5 if GWPn1 = GWPn0

r ← r + 4 if ADPn1 > ADPn0

r ← r + 4 if ADPn1 = ADPn0

r ← r + 3 if POCP n1 > POCP n0

r ← r + 3 if POCP n1 = POCP n0

r ← r + 2 if APn1 > AP n0

r ← r + 2 if APn1 = AP n0

r ← r + 1 if EPn1 > EPn0

r ← r + 1 if EPn1 = EPn0

r ← r + 4 if HTP n1 > HTP n0

r ← r + 4 if HTP n1 = HTP n0

return r

return r

Pplus3 = 5

Pegal3 = 0 47

Pplus3 + Pegal3

C21 :=

PT

= 0.263158

4. C23 (F2,F3 ) Calculam P+---->notat: Pplus Pplus4 :=

r←0

Pegal4 :=

r←0

r ← r + 5 if GWPn1 > GWPn2

r ← r + 5 if GWPn1 = GWPn2

r ← r + 4 if ADPn1 > ADPn2

r ← r + 4 if ADPn1 = ADPn2

r ← r + 3 if POCP n1 > POCP n2

r ← r + 3 if POCP n1 = POCP n2

r ← r + 2 if APn1 > AP n2

r ← r + 2 if APn1 = AP n2

r ← r + 1 if EPn1 > EPn2

r ← r + 1 if EPn1 = EPn2

r ← r + 4 if HTP n1 > HTP n2

r ← r + 4 if HTP n1 = HTP n2

return r

return r

Pplus4 = 5 C23 :=

Pegal4 = 0 Pplus4 + Pegal4 PT

= 0.263158

5. C31 (F3,F1 ) Calculam P+---->notat: Pplus Pplus5 :=

r←0

Pegal5 :=

r←0

r ← r + 5 if GWPn2 > GWPn0

r ← r + 5 if GWPn2 = GWPn0

r ← r + 4 if ADPn2 > ADPn0

r ← r + 4 if ADPn2 = ADPn0

r ← r + 3 if POCP n2 > POCP n0

r ← r + 3 if POCP n2 = POCP n0

r ← r + 2 if APn2 > AP n0

r ← r + 2 if APn2 = AP n0

r ← r + 1 if EPn2 > EPn0

r ← r + 1 if EPn2 = EPn0

r ← r + 4 if HTP n2 > HTP n0

r ← r + 4 if HTP n2 = HTP n0

return r

return r

Pplus5 = 14 C31 :=

Pegal5 = 5 Pplus5 + Pegal5 PT

=1

6. C32 (F3 ,F2) Calculam P+---->notat: Pplus

48

Pplus6 :=

r←0

Pegal6 :=

r←0

r ← r + 5 if GWPn2 > GWPn1

r ← r + 5 if GWPn2 = GWPn1

r ← r + 4 if ADPn2 > ADPn1

r ← r + 4 if ADPn2 = ADPn1

r ← r + 3 if POCP n2 > POCP n1

r ← r + 3 if POCP n2 = POCP n1

r ← r + 2 if APn2 > AP n1

r ← r + 2 if APn2 = AP n1

r ← r + 1 if EPn2 > EPn1

r ← r + 1 if EPn2 = EPn1

r ← r + 4 if HTP n2 > HTP n1

r ← r + 4 if HTP n2 = HTP n1

return r

return r

Pplus6 = 14 C32 :=

Pegal6 = 0 Pplus6 + Pegal6 PT

= 0.736842

Matricea de concordanta:

F1

F2 −−−

F1

F3

C12 = 0.736842

C13 = 0.263158 C23 = 0.263158

F2

C21 = 0.263158

−−−

F3

C31 = 1

C32 = 0.736842

−−−

Calculul matricii de nondiscordanta:

Se vor calcula indicii dupa cum urmeaza:

1.

D12 (F1,F2) Pminus1 :=

r←0

(

) ( ) r ← ADPn1 − ADPn0 if r < ( ADPn1 − ADPn0) ∧ ( ADPn0 < ADPn1) r ← POCP n1 − POCP n0 if r < ( POCP n1 − POCP n0) ∧ ( POCP n0 < POCP n1) r ← APn1 − AP n0 if r < ( APn1 − APn0) ∧ ( APn0 < AP n1) r ← EPn1 − EPn0 if r < ( EPn1 − EPn0) ∧ ( EPn0 < EPn1) r ← HTP n1 − HTP n0 if r < ( HTP n1 − HTP n0) ∧ ( HTP n0 < HTP n1) r ← GWPn1 − GWPn0 if r < GWPn1 − GWPn0 ∧ GWPn0 < GWPn1

return r Pminus1 = 0.871

49

α1 :=

r←0

( ) ( ) r ← δADP if r < ( ADPn1 − ADPn0) ∧ ( ADPn0 < ADPn1) r ← δPOCP if r < ( POCP n1 − POCP n0) ∧ ( POCP n0 < POCP n1) r ← δAP if r < ( APn1 − AP n0) ∧ ( AP n0 < APn1) r ← δEP if r < ( EPn1 − EPn0) ∧ ( EPn0 < EPn1) r ← δHTP if r < ( HTP n1 − HTP n0) ∧ ( HTP n0 < HTP n1) r ← δGWP if r < GWPn1 − GWPn0 ∧ GWPn0 < GWPn1

return r α1 = 0.871

D12 :=

2.

Pminus1 α1

=1

D13 (F1,F3) Pminus2 :=

r←0

(

) ( ) r ← ADPn2 − ADPn0 if r < ( ADPn2 − ADPn0) ∧ ( ADPn0 < ADPn2) r ← POCP n2 − POCP n0 if r < ( POCP n2 − POCP n0) ∧ ( POCP n0 < POCP n2) r ← APn2 − AP n0 if r < ( APn2 − APn0) ∧ ( APn0 < AP n2) r ← EPn2 − EPn0 if r < ( EPn2 − EPn0) ∧ ( EPn0 < EPn2) r ← HTP n2 − HTP n0 if r < ( HTP n2 − HTP n0) ∧ ( HTP n0 < HTP n2) r ← GWPn2 − GWPn0 if r < GWPn2 − GWPn0 ∧ GWPn0 < GWPn2

return r Pminus2 = 0.046 α2 :=

r←0

( ) ( ) r ← δADP if r < ( ADPn2 − ADPn0) ∧ ( ADPn0 < ADPn2) r ← δPOCP if r < ( POCP n2 − POCP n0) ∧ ( POCP n0 < POCP n2) r ← δAP if r < ( APn2 − AP n0) ∧ ( AP n0 < APn2) r ← δEP if r < ( EPn2 − EPn0) ∧ ( EPn0 < EPn2) r ← δHTP if r < ( HTP n2 − HTP n0) ∧ ( HTP n0 < HTP n2) r ← δGWP if r < GWPn2 − GWPn0 ∧ GWPn0 < GWPn2

return r α2 = 0.241

D13 :=

3

Pminus2 α2

= 0.189

D21 (F2,F1)

50

Pminus3 :=

r←0

(

) ( ) r ← ADPn0 − ADPn1 if r < ( ADPn0 − ADPn1) ∧ ( ADPn1 < ADPn0) r ← POCP n0 − POCP n1 if r < ( POCP n0 − POCP n1) ∧ ( POCP n1 < POCP n0) r ← APn0 − AP n1 if r < ( APn0 − APn1) ∧ ( APn1 < AP n0) r ← EPn0 − EPn1 if r < ( EPn0 − EPn1) ∧ ( EPn1 < EPn0) r ← HTP n0 − HTP n1 if r < ( HTP n0 − HTP n1) ∧ ( HTP n1 < HTP n0) r ← GWPn0 − GWPn1 if r < GWPn0 − GWPn1 ∧ GWPn1 < GWPn0

return r Pminus3 = 0.991 α3 :=

r←0

( ) ( ) r ← δADP if r < ( ADPn0 − ADPn1) ∧ ( ADPn1 < ADPn0) r ← δPOCP if r < ( POCP n0 − POCP n1) ∧ ( POCP n1 < POCP n0) r ← δAP if r < ( APn0 − AP n1) ∧ ( AP n1 < APn0) r ← δEP if r < ( EPn0 − EPn1) ∧ ( EPn1 < EPn0) r ← δHTP if r < ( HTP n0 − HTP n1) ∧ ( HTP n1 < HTP n0) r ← δGWP if r < GWPn0 − GWPn1 ∧ GWPn1 < GWPn0

return r α3 = 0.991

D21 :=

4.

Pminus3 α3

= 0.9996

D23 (F2,F3) Pminus4 :=

r←0

(

) ( ) r ← ADPn2 − ADPn1 if r < ( ADPn2 − ADPn1) ∧ ( ADPn1 < ADPn2) r ← POCP n2 − POCP n1 if r < ( POCP n2 − POCP n1) ∧ ( POCP n1 < POCP n2) r ← APn2 − AP n1 if r < ( APn2 − APn1) ∧ ( APn1 < AP n2) r ← EPn2 − EPn1 if r < ( EPn2 − EPn1) ∧ ( EPn1 < EPn2) r ← HTP n2 − HTP n1 if r < ( HTP n2 − HTP n1) ∧ ( HTP n1 < HTP n2) r ← GWPn2 − GWPn1 if r < GWPn2 − GWPn1 ∧ GWPn1 < GWPn2

return r Pminus4 = 0.991

51

α4 :=

r←0

( ) ( ) r ← δADP if r < ( ADPn2 − ADPn1) ∧ ( ADPn1 < ADPn2) r ← δPOCP if r < ( POCP n2 − POCP n1) ∧ ( POCP n1 < POCP n2) r ← δAP if r < ( APn2 − AP n1) ∧ ( AP n1 < APn2) r ← δEP if r < ( EPn2 − EPn1) ∧ ( EPn1 < EPn2) r ← δHTP if r < ( HTP n2 − HTP n1) ∧ ( HTP n1 < HTP n2) r ← δGWP if r < GWPn2 − GWPn1 ∧ GWPn1 < GWPn2

return r α4 = 0.991

D23 :=

5.

Pminus4 α4

=1

D31 (F3,F1) Pminus5 :=

r←0

(

) ( ) r ← ADPn0 − ADPn2 if r < ( ADPn2 − ADPn0) ∧ ( ADPn2 < ADPn0) r ← POCP n0 − POCP n2 if r < ( POCP n2 − POCP n0) ∧ ( POCP n2 < POCP n0) r ← APn0 − AP n2 if r < ( APn2 − APn0) ∧ ( APn2 < AP n0) r ← EPn0 − EPn2 if r < ( EPn2 − EPn0) ∧ ( EPn2 < EPn0) r ← HTP n0 − HTP n2 if r < ( HTP n2 − HTP n0) ∧ ( HTP n2 < HTP n0) r ← GWPn0 − GWPn2 if r < GWPn2 − GWPn0 ∧ GWPn2 < GWPn0

return r Pminus5 = 0 α5 :=

r←0

( ) ( ) r ← δADP if r < ( ADPn2 − ADPn0) ∧ ( ADPn2 < ADPn0) r ← δPOCP if r < ( POCP n2 − POCP n0) ∧ ( POCP n2 < POCP n0) r ← δAP if r < ( APn2 − AP n0) ∧ ( AP n2 < APn0) r ← δEP if r < ( EPn2 − EPn0) ∧ ( EPn2 < EPn0) r ← δHTP if r < ( HTP n2 − HTP n0) ∧ ( HTP n2 < HTP n0) r ← δGWP if r < GWPn2 − GWPn0 ∧ GWPn2 < GWPn0

return r α5 = 0

D31 :=

6.

Pminus5 α5

=

D32 (F3,F2)

52

Pminus6 :=

r←0

(

) ( ) r ← ADPn1 − ADPn2 if r < ( ADPn1 − ADPn2) ∧ ( ADPn2 < ADPn1) r ← POCP n1 − POCP n2 if r < ( POCP n1 − POCP n2) ∧ ( POCP n2 < POCP n1) r ← APn1 − AP n2 if r < ( APn1 − APn2) ∧ ( APn2 < AP n1) r ← EPn1 − EPn2 if r < ( EPn1 − EPn2) ∧ ( EPn2 < EPn1) r ← HTP n1 − HTP n2 if r < ( HTP n1 − HTP n2) ∧ ( HTP n2 < HTP n1) r ← GWPn1 − GWPn2 if r < GWPn1 − GWPn2 ∧ GWPn2 < GWPn1

return r Pminus6 = 0.825 α6 :=

r←0

( ) ( ) r ← δADP if r < ( ADPn1 − ADPn2) ∧ ( ADPn2 < ADPn1) r ← δPOCP if r < ( POCP n1 − POCP n2) ∧ ( POCP n2 < POCP n1) r ← δAP if r < ( APn1 − AP n2) ∧ ( AP n2 < APn1) r ← δEP if r < ( EPn1 − EPn2) ∧ ( EPn2 < EPn1) r ← δHTP if r < ( HTP n1 − HTP n2) ∧ ( HTP n2 < HTP n1) r ← δGWP if r < GWPn1 − GWPn2 ∧ GWPn2 < GWPn1

return r α6 = 0.871

D32 :=

Pminus6 α6

= 0.948

Matricea de nonconcordanta:

F1 F1

F2 −−−

F3

D12 = 1

D13 = 0.189 D23 = 1

F2

D21 = 0.9996

−−−

F3

D31

D32 = 0.948

−−−

53

6

× 10

54

6.819863 × 10

6

55

0.98953

0.045564

0.924404

0.991429

56