Ube Separation Membrane - Biogas Customer
This document was uploaded by user and they confirmed that they have the permission to share it. If you are author or own the copyright of this book, please report to us by using this DMCA report form. Report DMCA
Overview
Download & View Ube Separation Membrane - Biogas Customer as PDF for free.
More details
- Words: 1,097
- Pages: 18
Loading documents preview...
- CO2/CH4 Separation -
UBE’s Membrane Modules CONFIDENTIAL
Recovery of N2 from compressed air
Dehumidification of compressed air
N2
Air Dryer
Fire and explosion protection for oil and gas well injection, Blanket for tank, tire filling etc.
Instrument Air Medical Equipment Dry Box etc.
Dehydration from aqueous organic vapor
Separation H2 from hydrocarbons
Separation CO2 from hydrocarbons
Dehydration
H2
CO2
Bio-Ethanol i-Propanol Ketones etc.
H2 Recovery on Oil Refinery and Chemical Plants
Hydrocarbon (Methane) Enrichment from Landfill Gas, Biogas, and Natural Gas
2
History of UBE’s Membrane Business ・ 1978
Started R&D Work
・ 1981
Jointed MITI’s C1 Project (National Projects)
・ 1983
Field Tests at Ammonia Plant
・ 1985
Organized Membrane Dept.
・ 1986
Supply First Hydrogen Recovery Unit
・ 1989
First Membranes for CO2 & Dryer
・ 1992
First Membrane for N2/O2 Separation
・ 1993
New Membranes for H2 & CO2
・ 1999
Started EtOH Dehydration Commercial Plant
・ 2006
Expansion of Business mainly with N2/O2 Separator & Ethanol Dehydration Membrane
Permeation Rate
Permeation Rate
High Permeation
Low Permeation
H2O H2 CO2 O2
He H2S Ar
CO N2
CH4
C2H6 C3+ (Hydrocarbon)
Natural Gas treatment in Japan
Enhanced Oil Recovery (EOR) in Turkey
Landfill gas treatment in Germany
Application Examples - Environmental Application (CO2/CH4 Separation from Biogas)
Module Structure - CO2 Separation Off Gas (Permeate Gas)
Compressed Biogas
Product Gas (Non-Permeate Gas)
(Feed Gas)
CO2 Rich Gas
Compressed Biogas (Feed Gas)
Product Gas (Non-Permeate Gas) CH4 Rich Gas Polyimide Hollow Fiber
Environmental Application (CO2/CH4 Separation from Biogas) Methane Fermenter
Methane Fermentation Gas (CH4: 60%,CO2: 40%)
Livestock Dung Ovoid Shape Digestion Tank
CO2/CH4 Module UBE Membrane Module
Purified CH4 Household Sewage
Main Application - Alternative Natural Gas
(CH4: >95%） ）
Pipe Line Gas Natural Gas Vehicle Power Generator
Landfill Gas
CH4 is one of important greenhouse gases that have to be reduced, but it is 20 times more effective than CO2. CH4 should be separated and purified for effective utilization.
Durability against Contaminants
Water / Humidity: Liquid water should be avoided and less than 80 RH% Small Particles: As few as possible, less than 0.01 µm Residual Oil:
< 0.01mg/Nm3 (< 0.008 ppm w/w)
Hydrocarbons:
< 0.013mg/Nm3 (< 0.01 ppm w/w)
H2S:
< 3 vol%
NH3 & Amines:
< 100 vppm
Acid:
Should be avoided
Aromatics:
As low as possible
Alcohol:
Good
Environmental Application Typical Process Flow for Methane Separation Methane Fermenter Gas Cleaning
Compressor Landfill Gas
After Cooler
Mist Filter
Oil Filter
Carbon Bed
Dust Filter
Heater
UBE Membrane Module
Feed Gas
Product Gas (Non-Permeate Gas)
Off Gas (Permeate Gas)
Methane Rich Gas
CONFIDENTIAL
Application Examples - Environmental Application (CO2/CH4 Separation from Biogas)
11
Purification of Methane from Bio Gas CONFIDENTIAL
A. One Membrane and One Compressor UBE Membrane Module
Feed Gas CH4: 60.0% CO2: 40.0%
Product Gas CH4: 95.0 vol% Recovery: 76%
Off Gas
Material Balance Flow Pattern
Composition, Vol%
CH4 Recovery (%)
A
76
B
81
C
97
(1)
(2)
Feed
(3)
(4)
(5)
(6)
CH4 Rich
CO2 Rich
2nd Feed
Recycle
CO2
40.0
40.0
5.0
71.9
CH4
60.0
40.0
95.0
28.1
CO2
40.0
40.0
4.8
76.4
9.5
35.0
CH4
60.0
40.0
95.2
23.6
90.5
65.0
CO2
40.0
40.0
4.3
94.9
71.0
40.0
CH4
60.0
40.0
95.7
5.1
29.0
60.0
Ref.) N. Tanihara and M. Hayashi, Maku (Membrane), 35, 37 (2010).
12
Purification of Methane from Bio Gas CONFIDENTIAL
B. Two Membranes and One Compressor Compressor
1st Stage
Feed Gas CH4: 60.0% CO2: 40.0%
Product Gas CH4: 95.2 vol% Recovery: 81%
UBE Membrane Module
Off Gas UBE Membrane Module
2nd Stage
Material Balance Flow Pattern
Composition, Vol%
CH4 Recovery (%)
A
76
B
81
C
97
(1)
(2)
Feed
(3)
(4)
(5)
(6)
CH4 Rich
CO2 Rich
2nd Feed
Recycle
CO2
40.0
40.0
5.0
71.9
CH4
60.0
40.0
95.0
28.1
CO2
40.0
40.0
4.8
76.4
9.5
35.0
CH4
60.0
40.0
95.2
23.6
90.5
65.0
CO2
40.0
40.0
4.3
94.9
71.0
40.0
CH4
60.0
40.0
95.7
5.1
29.0
60.0
Ref.) N. Tanihara and M. Hayashi, Maku (Membrane), 35, 37 (2010).
13
Purification of Methane from Bio Gas CONFIDENTIAL
C. Two Membranes and Two Compressors 1st Stage
Feed Gas CH4: 60.0% CO2: 40.0%
Product Gas CH4: 95.7 vol% Recovery: 97%
UBE Membrane module
UBE Membrane module
2nd Stage
Compressor
Off Gas
Material Balance Flow Pattern
Composition, Vol%
CH4 Recovery (%)
A
76
B
81
C
97
(1)
(2)
Feed
(3)
(4)
(5)
(6)
CH4 Rich
CO2 Rich
2nd Feed
Recycle
CO2
40.0
40.0
5.0
71.9
CH4
60.0
40.0
95.0
28.1
CO2
40.0
40.0
4.8
76.4
9.5
35.0
CH4
60.0
40.0
95.2
23.6
90.5
65.0
CO2
40.0
40.0
4.3
94.9
71.0
40.0
CH4
60.0
40.0
95.7
5.1
29.0
60.0
Ref.) N. Tanihara and M. Hayashi, Maku (Membrane), 35, 37 (2010).
14
Purification of Methane from Bio Gas CONFIDENTIAL
Combination with Cryogenic CO2 Recovery Unit Compressor
Feed Gas CH4: 60.0% CO2: 40.0%
1st Stage
Product Gas CH4: 91.8 vol% Recovery: 95.7%
UBE Membrane Module
Off Gas CH4: 80% CO2: 20%
UBE Membrane Module
2nd Stage
Cryogenic CO2 Recovery Unit (CO2 >90% is needed)
High Purity CO2 (>99.9 vol%) Module 1st Stage CO-710F x 1 pc 2nd Stage CO-710F x 4 pcs Feed Gas Condition Flow Rate: 600 Nm3/hr Pressure: 1.00 MPaG Composition CH4: 60.0 vol% CO2: 40.0 vol%
Material Balance Feed Gas
Off Gas
Product Gas
Flow Rate,
Nm3/hr
600
292
393
Pressure,
MPaG
1.00
0.00
0.88
Temperature,
C˚
50
50
50
Composition,
vol%
CH4
60.0
5.66
91.80
CO2
40.0
94.34
8.20
15
Job Record for UBE CO2 Membrane Unit
No.
Application
Location
Pressure
Capacity
1
Landfill Gas
Germany
35 bar
200 Nm3/h
2
Landfill Gas
Netherlands
32 bar
350 Nm3/h
3
Natural Gas
Japan
68 bar
2,100 Nm3/h
4
Enhanced Oil
Turkey
55 bar
1,500 Nm3/h
5
CO2 Rejection
Germany
30 bar
30 Nm3/h
6
Landfill Gas
Netherlands
32 bar
350 Nm3/h
7
Landfill Gas
USA
75 bar
2,600 Nm3/h
8
Natural Gas
Canada
85 bar
25,000 Nm3/h
9
Landfill Gas
Netherlands
36 bar
350 Nm3/h
10
Synsesis Gas
Japan
7 bar
2,100 Nm3/h
11
Natural Gas
Italy
40 bar
3,100 Nm3/h
12
Natural Gas
Australia
121 bar
20,000 Nm3/h
13
BioGas (Sewage Fermentation)
Japan
7 bar
10 Nm3/h
14
BioGas (Livestock Dung Fermentation)
Japan
9 bar
20 Nm3/h
15
Landfill Gas
USA
13 bar
3,300 Nm3/h
16
BioGas
Netherlands
7.5 bar
1,500 Nm3/h
17
BioGas
Germany
8 bar
100 Nm3/h
18
BioGas
Netherland
8 bar
5 Nm3/h
Job Record for UBE CO2 Membrane Unit
Netherlands Netherlands
Germany Netherlands
Canada
Germany Germany
Netherlands
Italy
Japan Japan
Netherlands
USA USA
Turkey (Enhanced Oil)
Japan (Syn. Gas)
Japan
Natural Gas Australia
Biogas Landfill Gas Others
End
Membrane Group
UBE’s Membrane Modules CONFIDENTIAL
Recovery of N2 from compressed air
Dehumidification of compressed air
N2
Air Dryer
Fire and explosion protection for oil and gas well injection, Blanket for tank, tire filling etc.
Instrument Air Medical Equipment Dry Box etc.
Dehydration from aqueous organic vapor
Separation H2 from hydrocarbons
Separation CO2 from hydrocarbons
Dehydration
H2
CO2
Bio-Ethanol i-Propanol Ketones etc.
H2 Recovery on Oil Refinery and Chemical Plants
Hydrocarbon (Methane) Enrichment from Landfill Gas, Biogas, and Natural Gas
2
History of UBE’s Membrane Business ・ 1978
Started R&D Work
・ 1981
Jointed MITI’s C1 Project (National Projects)
・ 1983
Field Tests at Ammonia Plant
・ 1985
Organized Membrane Dept.
・ 1986
Supply First Hydrogen Recovery Unit
・ 1989
First Membranes for CO2 & Dryer
・ 1992
First Membrane for N2/O2 Separation
・ 1993
New Membranes for H2 & CO2
・ 1999
Started EtOH Dehydration Commercial Plant
・ 2006
Expansion of Business mainly with N2/O2 Separator & Ethanol Dehydration Membrane
Permeation Rate
Permeation Rate
High Permeation
Low Permeation
H2O H2 CO2 O2
He H2S Ar
CO N2
CH4
C2H6 C3+ (Hydrocarbon)
Natural Gas treatment in Japan
Enhanced Oil Recovery (EOR) in Turkey
Landfill gas treatment in Germany
Application Examples - Environmental Application (CO2/CH4 Separation from Biogas)
Module Structure - CO2 Separation Off Gas (Permeate Gas)
Compressed Biogas
Product Gas (Non-Permeate Gas)
(Feed Gas)
CO2 Rich Gas
Compressed Biogas (Feed Gas)
Product Gas (Non-Permeate Gas) CH4 Rich Gas Polyimide Hollow Fiber
Environmental Application (CO2/CH4 Separation from Biogas) Methane Fermenter
Methane Fermentation Gas (CH4: 60%,CO2: 40%)
Livestock Dung Ovoid Shape Digestion Tank
CO2/CH4 Module UBE Membrane Module
Purified CH4 Household Sewage
Main Application - Alternative Natural Gas
(CH4: >95%） ）
Pipe Line Gas Natural Gas Vehicle Power Generator
Landfill Gas
CH4 is one of important greenhouse gases that have to be reduced, but it is 20 times more effective than CO2. CH4 should be separated and purified for effective utilization.
Durability against Contaminants
Water / Humidity: Liquid water should be avoided and less than 80 RH% Small Particles: As few as possible, less than 0.01 µm Residual Oil:
< 0.01mg/Nm3 (< 0.008 ppm w/w)
Hydrocarbons:
< 0.013mg/Nm3 (< 0.01 ppm w/w)
H2S:
< 3 vol%
NH3 & Amines:
< 100 vppm
Acid:
Should be avoided
Aromatics:
As low as possible
Alcohol:
Good
Environmental Application Typical Process Flow for Methane Separation Methane Fermenter Gas Cleaning
Compressor Landfill Gas
After Cooler
Mist Filter
Oil Filter
Carbon Bed
Dust Filter
Heater
UBE Membrane Module
Feed Gas
Product Gas (Non-Permeate Gas)
Off Gas (Permeate Gas)
Methane Rich Gas
CONFIDENTIAL
Application Examples - Environmental Application (CO2/CH4 Separation from Biogas)
11
Purification of Methane from Bio Gas CONFIDENTIAL
A. One Membrane and One Compressor UBE Membrane Module
Feed Gas CH4: 60.0% CO2: 40.0%
Product Gas CH4: 95.0 vol% Recovery: 76%
Off Gas
Material Balance Flow Pattern
Composition, Vol%
CH4 Recovery (%)
A
76
B
81
C
97
(1)
(2)
Feed
(3)
(4)
(5)
(6)
CH4 Rich
CO2 Rich
2nd Feed
Recycle
CO2
40.0
40.0
5.0
71.9
CH4
60.0
40.0
95.0
28.1
CO2
40.0
40.0
4.8
76.4
9.5
35.0
CH4
60.0
40.0
95.2
23.6
90.5
65.0
CO2
40.0
40.0
4.3
94.9
71.0
40.0
CH4
60.0
40.0
95.7
5.1
29.0
60.0
Ref.) N. Tanihara and M. Hayashi, Maku (Membrane), 35, 37 (2010).
12
Purification of Methane from Bio Gas CONFIDENTIAL
B. Two Membranes and One Compressor Compressor
1st Stage
Feed Gas CH4: 60.0% CO2: 40.0%
Product Gas CH4: 95.2 vol% Recovery: 81%
UBE Membrane Module
Off Gas UBE Membrane Module
2nd Stage
Material Balance Flow Pattern
Composition, Vol%
CH4 Recovery (%)
A
76
B
81
C
97
(1)
(2)
Feed
(3)
(4)
(5)
(6)
CH4 Rich
CO2 Rich
2nd Feed
Recycle
CO2
40.0
40.0
5.0
71.9
CH4
60.0
40.0
95.0
28.1
CO2
40.0
40.0
4.8
76.4
9.5
35.0
CH4
60.0
40.0
95.2
23.6
90.5
65.0
CO2
40.0
40.0
4.3
94.9
71.0
40.0
CH4
60.0
40.0
95.7
5.1
29.0
60.0
Ref.) N. Tanihara and M. Hayashi, Maku (Membrane), 35, 37 (2010).
13
Purification of Methane from Bio Gas CONFIDENTIAL
C. Two Membranes and Two Compressors 1st Stage
Feed Gas CH4: 60.0% CO2: 40.0%
Product Gas CH4: 95.7 vol% Recovery: 97%
UBE Membrane module
UBE Membrane module
2nd Stage
Compressor
Off Gas
Material Balance Flow Pattern
Composition, Vol%
CH4 Recovery (%)
A
76
B
81
C
97
(1)
(2)
Feed
(3)
(4)
(5)
(6)
CH4 Rich
CO2 Rich
2nd Feed
Recycle
CO2
40.0
40.0
5.0
71.9
CH4
60.0
40.0
95.0
28.1
CO2
40.0
40.0
4.8
76.4
9.5
35.0
CH4
60.0
40.0
95.2
23.6
90.5
65.0
CO2
40.0
40.0
4.3
94.9
71.0
40.0
CH4
60.0
40.0
95.7
5.1
29.0
60.0
Ref.) N. Tanihara and M. Hayashi, Maku (Membrane), 35, 37 (2010).
14
Purification of Methane from Bio Gas CONFIDENTIAL
Combination with Cryogenic CO2 Recovery Unit Compressor
Feed Gas CH4: 60.0% CO2: 40.0%
1st Stage
Product Gas CH4: 91.8 vol% Recovery: 95.7%
UBE Membrane Module
Off Gas CH4: 80% CO2: 20%
UBE Membrane Module
2nd Stage
Cryogenic CO2 Recovery Unit (CO2 >90% is needed)
High Purity CO2 (>99.9 vol%) Module 1st Stage CO-710F x 1 pc 2nd Stage CO-710F x 4 pcs Feed Gas Condition Flow Rate: 600 Nm3/hr Pressure: 1.00 MPaG Composition CH4: 60.0 vol% CO2: 40.0 vol%
Material Balance Feed Gas
Off Gas
Product Gas
Flow Rate,
Nm3/hr
600
292
393
Pressure,
MPaG
1.00
0.00
0.88
Temperature,
C˚
50
50
50
Composition,
vol%
CH4
60.0
5.66
91.80
CO2
40.0
94.34
8.20
15
Job Record for UBE CO2 Membrane Unit
No.
Application
Location
Pressure
Capacity
1
Landfill Gas
Germany
35 bar
200 Nm3/h
2
Landfill Gas
Netherlands
32 bar
350 Nm3/h
3
Natural Gas
Japan
68 bar
2,100 Nm3/h
4
Enhanced Oil
Turkey
55 bar
1,500 Nm3/h
5
CO2 Rejection
Germany
30 bar
30 Nm3/h
6
Landfill Gas
Netherlands
32 bar
350 Nm3/h
7
Landfill Gas
USA
75 bar
2,600 Nm3/h
8
Natural Gas
Canada
85 bar
25,000 Nm3/h
9
Landfill Gas
Netherlands
36 bar
350 Nm3/h
10
Synsesis Gas
Japan
7 bar
2,100 Nm3/h
11
Natural Gas
Italy
40 bar
3,100 Nm3/h
12
Natural Gas
Australia
121 bar
20,000 Nm3/h
13
BioGas (Sewage Fermentation)
Japan
7 bar
10 Nm3/h
14
BioGas (Livestock Dung Fermentation)
Japan
9 bar
20 Nm3/h
15
Landfill Gas
USA
13 bar
3,300 Nm3/h
16
BioGas
Netherlands
7.5 bar
1,500 Nm3/h
17
BioGas
Germany
8 bar
100 Nm3/h
18
BioGas
Netherland
8 bar
5 Nm3/h
Job Record for UBE CO2 Membrane Unit
Netherlands Netherlands
Germany Netherlands
Canada
Germany Germany
Netherlands
Italy
Japan Japan
Netherlands
USA USA
Turkey (Enhanced Oil)
Japan (Syn. Gas)
Japan
Natural Gas Australia
Biogas Landfill Gas Others
End
Membrane Group
Related Documents
Ube Separation Membrane - Biogas Customer
March 2021 0
Membrane
January 2021 3
Biogas Ternak
February 2021 2
Membrane Bioreactors
January 2021 1
Membrane Bioreactor
January 2021 1
Customer-avatar.pdf
March 2021 0More Documents from "Vlp"
Ube Separation Membrane - Biogas Customer
March 2021 0
Smartprep.in
March 2021 0
Synopsis
January 2021 2
X Cbse Science Tutorials
January 2021 1
Dan Zanger Trading Method.pdf
January 2021 1