Fehlerkatalog Zink 021210

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Die  casjng  alloys  properjes  and  standards  -­‐  Comparison  with  most  used  materials   www.sdt-­‐diecasjng.com  

Zinc  Alloys  (omitted  alloys  6,  7  and  16)

Commercial  Name

Zamak3

Applicable  standard  in  Europe Designation  according European  standard  (EN) /  International  Standard  (ISO)

Applicable  standard  in  Japan Japan  standard  designation

ZP3 ZP0400 ZnAl4

MPa MPa GPa MPa  x  10³ % % MPa MPa Joules MPa Brinell x107N.m-­‐3/2 % % g/cm3 x10-­‐6/°C W/m/hr/m2 %  IACS MS/mm² μohm  -­‐  cm °C J/kg/°C

+/-­‐  µm mm shots/hour shots/hour shots*10³

ZP5 ZP0410 ZnAl4Cu1

HF

HF

AG-­‐41A

Aluminum  Alloys  (most  used) Zamak8

ZP8 ZP0810 ZnAl8Cu1 EAZALL

Zamak27

ZP12 ZP1110 ZnAl11Cu1

ZP27 ZP2720 ZnAl27Cu2

AlSi9Cu3

AlSi8Cu3

AlSi12

A360

ZA8

A380

AlSi9Cu3(Fe) EN46000

AlSi8Cu3 EN-­‐46200

AlSi12(Cu) EN47000

ADC10

AlSi8Cu3  (d)

ADC12

Plastics

Steel

AZ91

Steel

ABS

PA  66

PA66+PA6

50%  fiber

30%Nylon

EN1753

DIN1.0402

ISO  1874

ISO  1874

ISO  1874

ISO  1874

ISO  1875

25-­‐65 25  -­‐  65 1,79-­‐3,2 1606-­‐5903 1,7-­‐6 2  -­‐  110

55-­‐90 80 0,7-­‐1,8

40-­‐70 45 7,5-­‐27

240-­‐250 17,5-­‐18

n/a 155-­‐210 3.2  -­‐  12.7 n/a

9-­‐50

4-­‐15 25-­‐50

2

3-­‐5

no  break

no  break

8

too  soft

too  soft

too  soft

5 15 too  soft

CuZn38

CuZn35Pb2

B  85/B  85M  -­‐08

ZA12

ZA27

A380

A360

A380

A384

A380

A383

AISI1020

JIS  H  5302-­‐2000

ZDC2  (a)

ADC10

Hot  or  Cold  Chamber  High  Pressure  Die  Casting 221 308  (241) 96 33+ 2-­‐10  (16) 6.3 214  (214) 414  (414) 46  (44) 48 97  (72) 2.25 18 40 6.7 27.4 113 27 15-­‐16 6.37 381-­‐387 419 0.07 0.30 100 0.4

ADC11

AlSi9Cu3

H  5301-­‐1990 ZDC1  (a)

Brass

Magnesium

A384

EN1706-­‐2010  /  ISO3522-­‐2007(E)

ASTM-­‐B791

NADCA

AG-­‐43A

269 283 396 241(200) 331  (269) 397  (331) 276  (234) 96 96 91.7 33+ 33+ 2-­‐7  (13) 2-­‐7  (2) 5 5.3  (9.9) 3.6 6 262  (262) 317  (317) 600  (600) 641  (641) 52  (42) 38  (5) 38  (28) 57 59 114  (80) 130  (98) 68  HRB 93  (71) 2.1 19 19 41 42 6.7 6.8 6.6 27.4 27.8 26.2 109 105 113 26 25 15-­‐16 15-­‐16 6.54 6.85 380-­‐386 379-­‐390 377-­‐412 380-­‐384 419 419 403 0.08 0.08 0.30 0.30 0.3 0.3 100 100 100 100 0.4 0.5 0.4 0.3 Large  200-­‐500  Small  400-­‐1000  Tiny  2000-­‐3000 200  -­‐  3600 300  -­‐  2,000

Al-­‐Si12Cu

CC  HPDC 283-­‐296 374  (297) 96 33+ 4-­‐13  (18) 8 275  (228) 252  (172) 42  (24) 103  (91) 1.95 20 44 6.3 23.3 112 27.7 15-­‐16 6.2 375-­‐404 435 0.11 0.30 100 0.6

Die  casjng  alloy  selecjon  requires   Tooling Longest  tooling  life,  can  reach  several  million  shots.  Significant  long-­‐term  tooling  cost  savings evaluajon  not  only  of  physical  and   mechanical  properjes,   Fastest  /  cheaper  (hot-­‐chamber)  process  possible  on  smaller  parts.  Best  on    miniature  parts  with   and  chemical  composijon,  but  also  of   Cost inherent  alloy  characterisjcs  and  their   Multislide  process. effect  on  die  casjng   producjon  as  well  as  possible  machining   Heaviest  of  die  cast  alloys,  but  castable  with  thinner  walls  than  aluminum,  which  can  offset  the  weight   Weight   and  final  surface  finishing.   disadvantage.   This  table  includes  selected  die  casjng   and  other  special  characterisjcs  which   Dimensional   Best  of  castable  alloys  (except  ZA2),  normally  near  net  shape  achievable. Accuracy  and   are  usually  considered  in  selecjng  an   Best  part  to  part  stability alloy  for  a  specific  applicajon.   Complexity The  characterisjcs  are  rated  from  best  to     Structural   Highest   d uctility   and  impact  strength    (except  ZA2). poorest,    being    the  best  the  most   Properties  and Poor  hot  creep  performance desirable  and  poorest  being  the  least.   Wear  Resistance   In  applying  these  rajngs,  it  should  be   noted  that  all  the  alloys  have  sufficiently   Surface  Finish  &   Best  as-­‐cast  surface  finish  readily  accepts  electro  coatings  and  decorative  finishes.   good  characterisjcs  to  be  accepted  by   Coatings   users  and  producers  of  die  casjngs.  A   rajng  of    poorest  in  one  or  more   Corrosion   Good  as  cast  and  best  in  general  after  surface  treatment categories  would  not  rule  out  an  alloy  if   Resistance   other  atributes  are  parjcularly   favorable,  but  rajngs  of  poorest  may   Conductivity,  &   Best  electrical  conductor.  Good  heat  transfer   present  manufacturing  difficuljes.   EMI  /  RFI  Shielding   The  benefi  ts  of  consuljng  a  custom  die   caster  experienced  in  casjng  the    alloy   Zamak3 Zamak5 Zamak2 EZAC HF Zamak8 Material being   3.7-­‐4.3 3.7-­‐4.4 3.7-­‐4.5 4.3-­‐4.7 8.0-­‐8.8 Al% considered  are  clear.   <0.05 0.7-­‐1.25 2.7-­‐3.3 0.03 0.9-­‐1.1 Cu% Die  casjngs  are  not  usually  solujon  heat   0.02-­‐0.06 0.02-­‐0.06 0.02-­‐0.06 0.01 0,015-­‐0,03 Mg% treated.  Low-­‐temperature  aging   treatments  may  be  used  for  stress  relief   reminder reminder reminder reminder reminder Zn% Proprietary   or  dimensional  stability.   -­‐ -­‐ -­‐ -­‐ -­‐ Mn% Estern  Alloys   Only  for  Al  alloys  temper  may  be  given   Cr% chemical   to  improve  properjes.   composition,   Ti% Die  casjngs  are  not  generally  gas  or  arc   around  Al7.3   <0,05 <0,05 <0,05 <0.03 <0,05 Fe% welded  or  brazed.   and  Cu2.8  +   <0,03 <0,03 <0,03 <0,045 Si% Ti0.16   a nd   C r0.1 <0,02 <0,02 <0,02 <0,02 Ni% <0,005 <0,005 <0,005 <0.002 <0,006 Cd% <0,005 <0,005 <0,005 <0,003 <0,006 Pb% <0,002 <0,002 <0,002 <0,001 <0,003 Sn%

Others  each Others  tot.

Zamak12

EN12844-­‐1998  /  ISO15201-­‐2006(E)

ZP2 ZP0430 ZnAl4Cu3

ASTM-­‐B86 AG-­‐40A

Casting  technology  /  mfg  process Yield  Strength Ultimate  Tensile  Strength  (b) Youngs  Modulus Torsional  Modulus Elongation  at  Fmax  (b) Elongation  at  Fracture Shear  Strength Compressive  Yield  Stress Impact  Resistance  (b) Fatigue  Resistance  (5x10to8) Hardness  (b) Fracture  Toughness  Kic Damping  Capacity  @  35  MPa Damping  Capacity  @  100  MPa Density Coeff.  of  Thermal  Expansion   Thermal  Conductivity   Electrical  Conductivity Electrical  Conductivity Electrical  Resistivity Melting  Temperature  Range Specific  Heat  Capacity Coeff.  of  Friction Poisson  Ratio Typical  Precision  over  100  mm Min  Wall  Thickness Typical  Production  Speeds Productivity  Range Typical  Tool  Life

Zamak2

EN12844-­‐1998  /  ISO15201-­‐2006(E)

Applicable  standard  in  US  (ANSI  /  AA/  ASTM) Designation  according  US  standard

Zamak5

ADC10  (c)

ADC12  (c)

ADC10

ADC11

ADC12

Cold  Chamber  High  Pressure  Die  Casting

310-­‐331 404  (310) 86

359-­‐379 426  (359) 78

4-­‐10  (20) 5 296  (228) 269  (186) 28  (20)

2-­‐3.5  (3)

100  (91)

ADC3  (c)

325  (255) 258  (255) 12.7  (5) 119  (100)

6 24.1 116 28.3 16 6.1 377-­‐432 450

5 26 125 29.7 17 5.8 377-­‐484 525

0.30 250 0.9 200-­‐300 250 700

0.30 300 1.2 100-­‐300 175 500

Cold/Hot

CC  HPDC

Extrusion

Stamping

140 240 71 26.9

140 240

140 240 (71) (26.9)

170 317 71

160 317 71

165 330

157 241

154 228

111-­‐170 200-­‐260 44 16.5

120 280 110

330 435 105

345 440 200

<1 195

1

<1 186

3.5 180

3.5 190

2.5 200

1.5

1.4

4

30 295

35.8

120 75

4 140 80

7 138 108-­‐159 3.7  -­‐  6 50-­‐70 63-­‐85

3.4 60-­‐90 80 3.6(?) 1 4 2.79 21 110-­‐120 24 13-­‐17 6.4 538-­‐593 963

80

110-­‐130 14-­‐18

250-­‐350 1

4 60-­‐90 80 3.6(?) 1 4 2.65 20 130-­‐150 27 16-­‐22 7.5 516-­‐582 960

2.63 21 113

2.74 22 96.2 27

2.82 21 96.2 22

557-­‐596 963

540-­‐595 963

516-­‐582

250-­‐350 1

0.33 250-­‐349 0.3

0.33 250-­‐350 1.3 50  -­‐250 30  -­‐  350 80-­‐300

140 85

83

86

25 53 1.82 25.2  -­‐  26.0 51  -­‐  72.7 11.5  -­‐  12.1 6-­‐10 468-­‐598 1020

250-­‐350 1.3

Limited  tooling  life,  surface  appearance  quality  (cracks)  can  determinate  shorter  (<50K  shots)  tooling  life

Near  net  shape  achievable.   Longer  cycle  time

Lowest  cost  per  unit  volume.  Most  of  time  relevant  secondary  process  are  requested.  Most  of  time  assembly  interface  request  machining

Weight  reduction  compared  with   the  Zinc  family  of  alloys.  

Second  lowest  in  density  next  to  magnesium.  

Less  than  hot  chamber  but  better   than  Aluminum

Near  net  shape  are  possible,  but  accurate  interface  many  time  need  machining,  mainly  small  size  geometries Draft  allowance  on  holes  at  least  0.5  degree  per  side

Highest  yield  strength,  hot  creep   and  wear  resistance

Highest  Modulus  of  Elasticity,  poor  impact  strength,  can  be  further  improved  with  heat  treatments

Less  than  hot  chamber  but  better   than  Aluminum

 Good  choice  for  coating  processes  that  require  high  temperatures. Difficult  reach  high  cosmetic  standard  on  plated  parts

Good  as  cast  and  best  in  general   after  surface  treatment

As  cast  depend  of  the  alloy,  Good  after  coating

Good  electrical  conductor.  Good   heat  transfer  

Best  choice  for  heat  transfer.  Good  electrical  conductivity  

Zamak12 10.5-­‐11.5 0.9-­‐1.5 0,015-­‐0,03 reminder -­‐

Zamak27 24-­‐27 2.0-­‐2.5 0,01-­‐0,02 reminder -­‐

<0,07 <0,06 <0,02 <0,006 <0,006 <0,003

<0,1 <0,08 <0,02 <0,006 <0,006 <0,003

AlSi9Cu3(Fe) reminder 2,0-­‐4,0 0.05-­‐0.55 <1.2 <0.55 <0.15 <0.25 <1,3 8-­‐11 <0,55

AlSi8Cu3 reminder 2,0-­‐3.5 0.05-­‐0.55 <1.2 0.15-­‐0.65 <0.15 <0.25 <0.8 7.5-­‐9.5 <0,35

AlSi12(Cu) reminder <1 0.05-­‐0.55 <0.55 0.05-­‐0.55 <0.10 <0.20 <0,8 10,5-­‐13.5 <0,3

<0.35 <0.15 <0.05 <0.25

<0.35 <0.15 <0.05 <0.25

<0.20 <0.10 <0.05 <0.25

110 75

135

131

53-­‐86 0,4-­‐6,4 7 too  soft

8.5 20.3 30-­‐100 26 4-­‐15 6.6 885-­‐925 380

8.47 20.3 115 28 4-­‐15 6.6 885-­‐925 380

7.87 16 52 12.1

1.02-­‐1.21 50  -­‐  150 0,128-­‐0,19 n/a

1.07 60-­‐90

1.14 80-­‐120

1.65 40-­‐15

1.11-­‐1.68 17  -­‐  104 <1? n/a

15.9

10exp15

10exp12 260

10exp10 260

10exp11 325

486

1960-­‐2130 0.45

10exp12 260 1200-­‐2350

16.9

175 1.2  200  -­‐  275.   40  -­‐  2400 300-­‐500

Less  than  hot  chamber  but  better   than  Aluminum

High  Shrinkage  and  humidity  make close  tolerances  difficult  for  plastics  100  to  400   Function  of  composition  and  reinforcement  100-­‐2000

Notes:       Mechanical  &  Physical  Properjes    -­‐  the  values  in  Italic  are  not  stated  in   the  respecjve  standard,  they  are  from  literature.   Can  compete  with  aluminum  if  thinner  wall  sections  are  used.   The  values  from  different  standards  are  omen  from  different  test   methods  (specimen  size  ,  condijon,  temperature)     Lowest  density,  lower  than  plastic (a)  Japan  standard  for  zinc  alloy  is  slightly  different  in  chemical   composijon,  consequently    cannot  be  used      ISO,  EN  or  US  alloy  as   Comparable  with  zinc  alloys subsjtujon  even  if  mechanical  properjes    are  technically  same.     Highest  strength-­‐to-­‐weight  ratio,  best  vibration  dampening.  Poorest   (b)  Only  for  zinc  alloys,  when  2  values,  the    one    between  brackets  is   referred  to  aged  condijon,  ageing  at  environmental  temperature  is   impact  strength.   reached  over  5  year,  arjficial  ageing  can  be  performed  at  100C  during  3   hours.   Good  as-­‐cast  surface  finishes  can  be  achieved. Especially  ZA2  has  big  decreasing    of  impact  resistance  amer  ageing  .   Difficult  to  electroplating   (c)  Japanese  specificajons  allow  0.3  magnesium  maximum.  Japanese   Difficult  to  reach  high  salt  spray  resistance. specificajons  allow  1.0  zinc  maximum.       (d)  EN  spec.  allows  1.2  max  zinc  and  up  to  0.5  max  magnesium.     Good  electro-­‐magnetic  shielding   DIN  1725  spec  allows  0.3  max  magnesium,    alloy  composijons  shown       Brass Magnesium Steel (e)  EN  spec.  tend  to  be  “primary  based”  and  have  low  impurity  limits   8,3-­‐9,7 making  it  difficults  to  correlate  directly  to  U.S.  and  /  or  Japanese  alloys.   <0,030 60-­‐65 60-­‐65   reminder   0,35-­‐1,0 30-­‐37 30-­‐37 Rev.  06    13DEC14   Longer  life  than  aluminum,  less  than  half  of  zinc

A360 reminder <0.6 0.4-­‐0.6 <0.5 <0.35

A380 reminder 3,0-­‐4,0 <0,1 <3,0 <0,5

A384 reminder 3,0-­‐4,5 <0,1 <3,0 <0,5

ADC10 reminder 2.0-­‐4.0 <0.3 <1 <0.5

ADC11 reminder 2.5-­‐4.0 <0.3 <1.2 <0.6

ADC12 reminder 1.5-­‐3.5 <0.3 <1 <0.5

<1.3 9-­‐10 <0,5

<2 7,5-­‐9,5 <0,5

<1.3 10,5-­‐12 <0,5

<1.3 7.5-­‐9.5 <0.5

<0.2 <1.3 7.5-­‐9.5 <0.5

<1.3 9.6-­‐12 <0.5

<0.2

<0.3 <0.2

0,15-­‐0,50

0,3-­‐0,6

<0,005 <0,10 <0,002

<0,1

0,17-­‐0,23

<0.25

<0,5

<0,5

<1 <0.2

Injection  Molding

0,8-­‐1,4

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